The microwave spectrum of NiH

Timothy Steimle, David F. Nachman, Jeffrey E. Shirley, David A. Fletcher, John M. Brown

Research output: Contribution to journalArticlepeer-review

19 Scopus citations


Numerous microwave transitions between the A-doubling components of vibrational levels in the X2Δ3/2 (ν = 0) state of NiH in the gas phase have been measured using the technique of microwave-optical double resonance (MODR) spectroscopy. An effective experimental method for the simultaneous introduction of low-frequency microwave radiation and optical laser radiation into a flowing reaction chamber has been demonstrated. Some A-doubling and magnetic hyperfine parameters were obtained from a least squares fit of an effective hamiltonian model to the observed transition frequencies. The spectroscopic parameters are interpreted in terms of the proposed electronic wavefunc-tions and state distribution.

Original languageEnglish (US)
Pages (from-to)923-932
Number of pages10
JournalMolecular Physics
Issue number5
StatePublished - Apr 1990

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry


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