The lambda-doubling spectrum of 13CH, studied by microwave optical double resonance

Timothy Steimle; David R. Woodward; John M. Brown

doi:10.1063/1.451265

The lambda-doubling spectrum of ¹³CH, studied by microwave optical double resonance

Timothy Steimle, David R. Woodward, John M. Brown

Molecular Sciences, School of (SMS)

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44 Scopus citations

Abstract

Lambda-doubling transitions in ¹³CH in its X ²Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The ¹³C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X ²Π state.

Original language	English (US)
Pages (from-to)	1276-1282
Number of pages	7
Journal	The Journal of chemical physics
Volume	85
Issue number	3
DOIs	https://doi.org/10.1063/1.451265
State	Published - 1985

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.451265

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title = "The lambda-doubling spectrum of 13CH, studied by microwave optical double resonance",

abstract = "Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.",

author = "Timothy Steimle and Woodward, {David R.} and Brown, {John M.}",

year = "1985",

doi = "10.1063/1.451265",

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AU - Steimle, Timothy

AU - Woodward, David R.

AU - Brown, John M.

PY - 1985

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N2 - Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.

AB - Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.

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The lambda-doubling spectrum of ¹³CH, studied by microwave optical double resonance

Abstract

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