Abstract
Thermochromic vanadium dioxide (VO2 ) thin films have been deposited on quartz substrates via a two-step furnace oxidation method. First pure 2 metallic vanadium thin films are deposited on quartz substrates using electron beam evaporation. Then the vanadium films are oxidized in an atmospheric tube furnace to produce stoichiometric VO . X-ray diffraction measurements confirm the composition of the prepared films. Temperature- dependent spectral transmittance measurements within the optical range reveal a 57% change upon transition at a wavelength of λ = 2.5 μm, indicating good potential for energy applications. The heating and cooling behaviors of the VO thin films on quartz are also investigated, and the VO transitions 2 2 from an insulator to a metal at 345 K upon heating. There is approximately 20 K of hysteresis between the heating and cooling curves. The dielectric constants of the furnace oxidized VO for both the insulating and metallic phases are fitted to a dispersion model for the visible and near-infrared regime. 2 Excellent thermal stability of the fabricated VO thin film from cryogenic to high temperatures is shown with in-situ optical measurements.
Original language | English (US) |
---|---|
Pages (from-to) | 62-67 |
Number of pages | 6 |
Journal | ES Materials and Manufacturing |
Volume | 6 |
DOIs | |
State | Published - Dec 2019 |
Keywords
- Optical characterization
- Property fitting
- Thermochromic
- Vanadium dioxide
ASJC Scopus subject areas
- Building and Construction
- Ceramics and Composites
- Metals and Alloys
- Polymers and Plastics
- Applied Mathematics
- Modeling and Simulation
- Numerical Analysis