TY - JOUR
T1 - Surmounting potential barriers
T2 - Hydrodynamic memory hedges against thermal fluctuations in particle transport
AU - Seyler, Sean L.
AU - Pressé, Steve
N1 - Funding Information:
ACKNOWLEDGMENTS The authors are indebted to Julian Lee and Charles E. Seyler for fruitful discussions and critical feedback on this manuscript. This work was supported by ARO Grant No. W911NF-17-1-0162 on "Multi-Dimensional and Dissipative Dynamical Systems: Maximum Entropy as a Principle for Modeling Dynamics and Emergent Phenomena in Complex Systems."
Funding Information:
The authors are indebted to Julian Lee and Charles E. Seyler for fruitful discussions and critical feedback on this manuscript. This work was supported by ARO Grant No. W911NF-17-1-0162 on “Multi-Dimensional and Dissipative Dynamical Systems: Maximum Entropy as a Principle for Modeling Dynamics and Emergent Phenomena in Complex Systems.”
Publisher Copyright:
© 2020 Author(s).
PY - 2020/7/28
Y1 - 2020/7/28
N2 - Recently, trapped-particle experiments have probed the instantaneous velocity of Brownian motion revealing that, at early times, hydrodynamic history forces dominate Stokes damping. In these experiments, nonuniform particle motion is well described by the Basset-Boussinesq-Oseen (BBO) equation, which captures the unsteady Basset history force at a low Reynolds number. Building off of these results, earlier we showed that, at low temperature, BBO particles could exploit fluid inertia in order to overcome potential barriers (generically modeled as a tilted washboard), while its Langevin counter-part could not. Here, we explore the behavior of neutrally buoyant BBO particles at finite temperature for moderate Stokes damping. Remarkably, we find that the transport of particles injected into a bumpy potential with sufficiently high barriers can be completely quenched at intermediate temperatures, whereas itinerancy may be possible above and below that temperature window. This effect is present for both Langevin and BBO dynamics, though these occur over drastically different temperature ranges. Furthermore, hydrodynamic memory mitigates these effects by sustaining initial particle momentum, even in the difficult intermediate temperature regime.
AB - Recently, trapped-particle experiments have probed the instantaneous velocity of Brownian motion revealing that, at early times, hydrodynamic history forces dominate Stokes damping. In these experiments, nonuniform particle motion is well described by the Basset-Boussinesq-Oseen (BBO) equation, which captures the unsteady Basset history force at a low Reynolds number. Building off of these results, earlier we showed that, at low temperature, BBO particles could exploit fluid inertia in order to overcome potential barriers (generically modeled as a tilted washboard), while its Langevin counter-part could not. Here, we explore the behavior of neutrally buoyant BBO particles at finite temperature for moderate Stokes damping. Remarkably, we find that the transport of particles injected into a bumpy potential with sufficiently high barriers can be completely quenched at intermediate temperatures, whereas itinerancy may be possible above and below that temperature window. This effect is present for both Langevin and BBO dynamics, though these occur over drastically different temperature ranges. Furthermore, hydrodynamic memory mitigates these effects by sustaining initial particle momentum, even in the difficult intermediate temperature regime.
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U2 - 10.1063/5.0013722
DO - 10.1063/5.0013722
M3 - Article
C2 - 32752686
AN - SCOPUS:85089131868
SN - 0021-9606
VL - 153
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 4
M1 - 0441102
ER -