Structures and properties of metal-ammonia compounds on the trail of a new ammonia geometry

W. S. Glaunsinger; R. B. Von Dreele; R. F. Marzke; R. C. Hanson; P. Chieux; P. Damay; R. Catterall

doi:10.1021/j150661a035

Structures and properties of metal-ammonia compounds on the trail of a new ammonia geometry

W. S. Glaunsinger, R. B. Von Dreele, R. F. Marzke, R. C. Hanson, P. Chieux, P. Damay, R. Catterall

Physics

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25 Scopus citations

Abstract

The ammonia molecules in metallic metal-hexaammine compounds apparently adopt a nearly planar, distorted structure containing one short and two extremely long bonds, rather than its normal pyramidal geometry containing equivalent protons. The experimental research on the structures and properties of metal-ammonia compounds related to this highly distorted structure is reviewed in detail, and the possible origin of this novel geometry is discussed.

Original language	English (US)
Pages (from-to)	3860-3877
Number of pages	18
Journal	Journal of physical chemistry
Volume	88
Issue number	17
DOIs	https://doi.org/10.1021/j150661a035
State	Published - Jan 1 1984

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

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10.1021/j150661a035

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abstract = "The ammonia molecules in metallic metal-hexaammine compounds apparently adopt a nearly planar, distorted structure containing one short and two extremely long bonds, rather than its normal pyramidal geometry containing equivalent protons. The experimental research on the structures and properties of metal-ammonia compounds related to this highly distorted structure is reviewed in detail, and the possible origin of this novel geometry is discussed.",

author = "Glaunsinger, {W. S.} and {Von Dreele}, {R. B.} and Marzke, {R. F.} and Hanson, {R. C.} and P. Chieux and P. Damay and R. Catterall",

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AU - Glaunsinger, W. S.

AU - Von Dreele, R. B.

AU - Marzke, R. F.

AU - Hanson, R. C.

AU - Chieux, P.

AU - Damay, P.

AU - Catterall, R.

PY - 1984/1/1

Y1 - 1984/1/1

N2 - The ammonia molecules in metallic metal-hexaammine compounds apparently adopt a nearly planar, distorted structure containing one short and two extremely long bonds, rather than its normal pyramidal geometry containing equivalent protons. The experimental research on the structures and properties of metal-ammonia compounds related to this highly distorted structure is reviewed in detail, and the possible origin of this novel geometry is discussed.

AB - The ammonia molecules in metallic metal-hexaammine compounds apparently adopt a nearly planar, distorted structure containing one short and two extremely long bonds, rather than its normal pyramidal geometry containing equivalent protons. The experimental research on the structures and properties of metal-ammonia compounds related to this highly distorted structure is reviewed in detail, and the possible origin of this novel geometry is discussed.

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Structures and properties of metal-ammonia compounds on the trail of a new ammonia geometry

Abstract

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