Structural environment of Al dissolved in 2PbO.B2O3 glasses used for solution calorimetry: an 27Al NMR study.

R. Oestrike; A. Navrotsky; G. L. Turner; B. Montez; R. J. Kirkpatrick

Structural environment of Al dissolved in 2PbO.B₂O₃ glasses used for solution calorimetry: an ²⁷Al NMR study.

R. Oestrike, A. Navrotsky, G. L. Turner, B. Montez, R. J. Kirkpatrick

Research output: Contribution to journal › Article › peer-review

Abstract

The ²⁷Al NMR spectroscopy of glassy 2PbO.B₂O₃ calorimetric fluxes containing from 1.0 to 23.8 mol.% Al (from dissolved alpha -Al₂O₃ or NaAlSi₃O₈ (albite) glass) shows that approx 92% of the Al is in four-fold coordination to oxygen (Al(4)), with the remainder mostly in six-fold coordination to oxygen (Al(6)) and that the chemical shifts and Al(4)/Al(6) ratios do not change measurably in this composition range. -J.A.Z.

Original language	English (US)
Pages (from-to)	788-791
Number of pages	4
Journal	American Mineralogist
Volume	72
Issue number	7-8
State	Published - 1987
Externally published	Yes

ASJC Scopus subject areas

Geophysics
Geochemistry and Petrology

Cite this

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title = "Structural environment of Al dissolved in 2PbO.B2O3 glasses used for solution calorimetry: an 27Al NMR study.",

abstract = "The 27Al NMR spectroscopy of glassy 2PbO.B2O3 calorimetric fluxes containing from 1.0 to 23.8 mol.% Al (from dissolved alpha -Al2O3 or NaAlSi3O8 (albite) glass) shows that approx 92% of the Al is in four-fold coordination to oxygen (Al(4)), with the remainder mostly in six-fold coordination to oxygen (Al(6)) and that the chemical shifts and Al(4)/Al(6) ratios do not change measurably in this composition range. -J.A.Z.",

author = "R. Oestrike and A. Navrotsky and Turner, {G. L.} and B. Montez and Kirkpatrick, {R. J.}",

year = "1987",

language = "English (US)",

volume = "72",

pages = "788--791",

journal = "American Mineralogist",

issn = "0003-004X",

publisher = "Mineralogical Society of America",

number = "7-8",

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TY - JOUR

T1 - Structural environment of Al dissolved in 2PbO.B2O3 glasses used for solution calorimetry

T2 - an 27Al NMR study.

AU - Oestrike, R.

AU - Navrotsky, A.

AU - Turner, G. L.

AU - Montez, B.

AU - Kirkpatrick, R. J.

PY - 1987

Y1 - 1987

N2 - The 27Al NMR spectroscopy of glassy 2PbO.B2O3 calorimetric fluxes containing from 1.0 to 23.8 mol.% Al (from dissolved alpha -Al2O3 or NaAlSi3O8 (albite) glass) shows that approx 92% of the Al is in four-fold coordination to oxygen (Al(4)), with the remainder mostly in six-fold coordination to oxygen (Al(6)) and that the chemical shifts and Al(4)/Al(6) ratios do not change measurably in this composition range. -J.A.Z.

AB - The 27Al NMR spectroscopy of glassy 2PbO.B2O3 calorimetric fluxes containing from 1.0 to 23.8 mol.% Al (from dissolved alpha -Al2O3 or NaAlSi3O8 (albite) glass) shows that approx 92% of the Al is in four-fold coordination to oxygen (Al(4)), with the remainder mostly in six-fold coordination to oxygen (Al(6)) and that the chemical shifts and Al(4)/Al(6) ratios do not change measurably in this composition range. -J.A.Z.

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SN - 0003-004X

VL - 72

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EP - 791

JO - American Mineralogist

JF - American Mineralogist

IS - 7-8

ER -

Structural environment of Al dissolved in 2PbO.B₂O₃ glasses used for solution calorimetry: an ²⁷Al NMR study.

Abstract

ASJC Scopus subject areas

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