Protoanthophyllite from three metamorphosed serpentinites

Hiromi Konishi, István Dódony, P R Buseck

Research output: Contribution to journalArticlepeer-review

6 Scopus citations


This is the first report of a natural Mg-rich protoanthophyllite. It is common in metamorphosed serpentinites from three Japanese ultramafic complexes, and some crystals contain anthophyllite (Pnma) lamellae. The Mg/(Mg + Fe) ratios of the Hayachine, Tari-Misaka, and Takase protoanthophyllites are 0.90,0.92, and 0.91, respectively. The samples have identical optical properties: X = a, Y = b. Z = c, and 2Vx = 64 ± 5°. Their space group is Pnmn (or Pn2n), as revealed by systematic extinctions in selected-area electron-diffraction patterns. The protoanthophyllite and anthophyllite have similar compositions and orthorhombic symmetry. They are difficult to distinguish using optical, microanalytical, and powder X-ray diffraction measurements. This problem raises the possibility that some of the published data on geological and synthetic anthophyllite samples may be of misidentified materials, potentially leading to errors in the published stability relations of anthophyllite. We provide a method to identify protoanthophyllite and differentiate it from its polymorphs using selected-area electron diffraction and high-resolution transmission electron microscopy methods.

Original languageEnglish (US)
Pages (from-to)1096-1103
Number of pages8
JournalAmerican Mineralogist
Issue number8-9
StatePublished - Jan 1 2002

ASJC Scopus subject areas

  • Geophysics
  • Geochemistry and Petrology


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