TY - JOUR
T1 - Plasmonic Vertically Coupled Complementary Antennas for Dual-Mode Infrared Molecule Sensing
AU - Chen, Xiahui
AU - Wang, Chu
AU - Yao, Yu
AU - Wang, Chao
N1 - Funding Information:
The research was supported by the startup funds provided to Y.Y. and C.W. by the School of Electrical, Computer & Energy Engineering at Arizona State University. C.W. thanks Prof. S. Y. Chou, Dr. L. Zhou, and Q. Zhang at Princeton University for valuable discussions. The VCCA sensors were fabricated in the ASU Nanofab with support from the cleanroom staff members.
Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/8/22
Y1 - 2017/8/22
N2 - Here we report an infrared plasmonic nanosensor for label-free, sensitive, specific, and quantitative identification of nanometer-sized molecules. The device design is based on vertically coupled complementary antennas (VCCAs) with densely patterned hot-spots. The elevated metallic nanobars and complementary nanoslits in the substrate strongly couple at vertical nanogaps between them, resulting in dual-mode sensing dependent on the light polarization parallel or perpendicular to the nanobars. We demonstrate experimentally that a monolayer of octadecanethiol (ODT) molecules (thickness 2.5 nm) leads to significant antenna resonance wavelength shift over 136 nm in the parallel mode, corresponding to 7.5 nm for each carbon atom in the molecular chain or 54 nm for each nanometer in analyte thickness. Additionally, all four characteristic vibrational fingerprint signals, including the weak CH3 modes, are clearly delineated experimentally in both sensing modes. Such a dual-mode sensing with a broad wavelength design range (2.5 to 4.5 μm) is potentially useful for multianalyte detection. Additionally, we create a mathematical algorithm to design gold nanoparticles on VCCA sensors in simulation with their morphologies statistically identical to those in experiments and systematically investigate the impact of the nanoparticle morphology on the nanosensor performance. The nanoparticles form dense hot-spots, promote molecular adsorption, enhance near-field intensity 103 to 104 times, and improve ODT refractometric and fingerprint sensitivities. Our VCCA sensor structure offers a great design flexibility, dual-mode operation, and high detection sensitivity, making it feasible for broad applications from biomarker detection to environment monitoring and energy harvesting.
AB - Here we report an infrared plasmonic nanosensor for label-free, sensitive, specific, and quantitative identification of nanometer-sized molecules. The device design is based on vertically coupled complementary antennas (VCCAs) with densely patterned hot-spots. The elevated metallic nanobars and complementary nanoslits in the substrate strongly couple at vertical nanogaps between them, resulting in dual-mode sensing dependent on the light polarization parallel or perpendicular to the nanobars. We demonstrate experimentally that a monolayer of octadecanethiol (ODT) molecules (thickness 2.5 nm) leads to significant antenna resonance wavelength shift over 136 nm in the parallel mode, corresponding to 7.5 nm for each carbon atom in the molecular chain or 54 nm for each nanometer in analyte thickness. Additionally, all four characteristic vibrational fingerprint signals, including the weak CH3 modes, are clearly delineated experimentally in both sensing modes. Such a dual-mode sensing with a broad wavelength design range (2.5 to 4.5 μm) is potentially useful for multianalyte detection. Additionally, we create a mathematical algorithm to design gold nanoparticles on VCCA sensors in simulation with their morphologies statistically identical to those in experiments and systematically investigate the impact of the nanoparticle morphology on the nanosensor performance. The nanoparticles form dense hot-spots, promote molecular adsorption, enhance near-field intensity 103 to 104 times, and improve ODT refractometric and fingerprint sensitivities. Our VCCA sensor structure offers a great design flexibility, dual-mode operation, and high detection sensitivity, making it feasible for broad applications from biomarker detection to environment monitoring and energy harvesting.
KW - molecular fingerprint
KW - near-field enhancement
KW - plasmonic nanoantennas
KW - refractometric sensing
KW - self-assembled gold nanoparticles
KW - surface-enhanced infrared absorption
KW - vibrational spectroscopy
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U2 - 10.1021/acsnano.7b02687
DO - 10.1021/acsnano.7b02687
M3 - Article
C2 - 28693314
AN - SCOPUS:85028460185
SN - 1936-0851
VL - 11
SP - 8034
EP - 8046
JO - ACS nano
JF - ACS nano
IS - 8
ER -