Abstract
This article highlights the utilization of phosphine-containing redox-active ligands for efficient hydrosilylation catalysis. Manganese, iron, cobalt, and nickel precatalysts featuring these chelates have been described and leading activities for carbonyl, carboxylate, and ester C-O bond hydrosilylation have been achieved. Mechanistic studies have provided insight into the importance of phosphine hemilability.
Original language | English (US) |
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Pages (from-to) | 15973-15977 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 50 |
Issue number | 44 |
DOIs | |
State | Published - Nov 28 2021 |
ASJC Scopus subject areas
- Inorganic Chemistry