Phosphorous-substituted redox-active ligands in base metal hydrosilylation catalysis

Anuja Sharma, Ryan J. Trovitch

Research output: Contribution to journalArticlepeer-review

4 Scopus citations


This article highlights the utilization of phosphine-containing redox-active ligands for efficient hydrosilylation catalysis. Manganese, iron, cobalt, and nickel precatalysts featuring these chelates have been described and leading activities for carbonyl, carboxylate, and ester C-O bond hydrosilylation have been achieved. Mechanistic studies have provided insight into the importance of phosphine hemilability.

Original languageEnglish (US)
Pages (from-to)15973-15977
Number of pages5
JournalDalton Transactions
Issue number44
StatePublished - Nov 28 2021

ASJC Scopus subject areas

  • Inorganic Chemistry


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