Abstract
Conventional dielectricε*(ω) data and solvation dynamic C(t) data are recorded simultaneously, assuring perfect coincidence of experimental conditions for the two relaxation phenomena in the glass-former 2-MTHF doped with quinoxaline. The dynamic MSA theory for dipolar solvation turns out to relate the observed Stokes-shift dynamics to the dielectric data in a quantitative fashion. The agreement between theory and experiment facilitates access to "microscopic" dielectric relaxation via spectroscopy of appropriate molecular probes in supercooled liquids.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 355-359 |
| Number of pages | 5 |
| Journal | Chemical Physics Letters |
| Volume | 199 |
| Issue number | 3-4 |
| DOIs | |
| State | Published - Nov 6 1992 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry