We report on the glass-forming abilities of the homologous series 1,2-diphenylcyclo-butene, pentene, hexene and heptene-a series that retains the cis-phenyl configuration characteristic of the well-studied glass former, o-terphenyl. We find that the glass-forming ability shows a sharp maximum for the six-membered ring and demonstrate that this trend in glass-forming ability is a consequence of a maximum, for the 1,2-diphenylcyclohexene, of the reduced glass transition temperature Tg/Tm. Since the nonmonotonic trend in Tg/Tm is entirely due to variations in T m, we conclude that the design target for maximizing the glass-forming ability across an homologous series should focus on the crystal stability and the factors that determine it.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films
- Materials Chemistry
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Ping, W. (Creator), Paraska, D. (Creator), Baker, R. (Creator), Harrowell, P. (Creator), Angell, C. A. (Creator) & Baker, R. (Creator), The Cambridge Structural Database, 2014