TY - JOUR
T1 - Microwave sintering of 8 mol% yttria-zirconia (8YZ)
T2 - An inert matrix material for nuclear fuel applications
AU - Thridandapani, R. R.
AU - Folgar, C. E.
AU - Folz, D. C.
AU - Clark, D. E.
AU - Wheeler, K.
AU - Peralta, Pedro
N1 - Funding Information:
The microwave processing research facility team at Virginia Tech gratefully acknowledges the Department of Energy for funding this work under Project No. DE-FC07-06-ID14731. In addition, work performed at Arizona State University was supported under the Global Nuclear Energy Partnership and the Advanced Fuel Cycle Initiative DOE/NE Agreement No. DE-FC07-05-ID14654.
PY - 2009/2/15
Y1 - 2009/2/15
N2 - This study focused on reducing overall processing time and temperature for fully stabilized zirconia, an inert matrix material candidate, to minimize the loss of actinides (that will be incorporated into the matrix material), while maintaining at least 90% theoretical density (TD). The effects of different processing routes on bulk density and microstructure were evaluated. The results obtained by adopting microwave sintering for 8 mol% Y2O3-ZrO2 were compared to conventional sintering. A 20 min soak time at 1300 °C resulted in pellets with 90% TD for microwave-processed samples, compared to 77% TD for pellets processed conventionally. A similar density was obtained at lower temperature (1200 °C) by increasing the soak time to 100 min in microwave processing. This time and temperature resulted in 60% TD conventionally processed pellets. Compressive strength values obtained for a 1300 °C (20 min soak time) microwave-processed sample were higher (1600 MPa) as compared to a conventionally processed sample (1300 MPa).
AB - This study focused on reducing overall processing time and temperature for fully stabilized zirconia, an inert matrix material candidate, to minimize the loss of actinides (that will be incorporated into the matrix material), while maintaining at least 90% theoretical density (TD). The effects of different processing routes on bulk density and microstructure were evaluated. The results obtained by adopting microwave sintering for 8 mol% Y2O3-ZrO2 were compared to conventional sintering. A 20 min soak time at 1300 °C resulted in pellets with 90% TD for microwave-processed samples, compared to 77% TD for pellets processed conventionally. A similar density was obtained at lower temperature (1200 °C) by increasing the soak time to 100 min in microwave processing. This time and temperature resulted in 60% TD conventionally processed pellets. Compressive strength values obtained for a 1300 °C (20 min soak time) microwave-processed sample were higher (1600 MPa) as compared to a conventionally processed sample (1300 MPa).
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U2 - 10.1016/j.jnucmat.2008.11.010
DO - 10.1016/j.jnucmat.2008.11.010
M3 - Article
AN - SCOPUS:58649092172
SN - 0022-3115
VL - 384
SP - 153
EP - 157
JO - Journal of Nuclear Materials
JF - Journal of Nuclear Materials
IS - 2
ER -