Isotopically resolved Raman spectra of C60

S. Guha; Jose Menendez; J. B. Page; G. B. Adams; G. S. Spencer; J. P. Lehman; P. Giannozzi; S. Baroni

doi:10.1103/PhysRevLett.72.3359

Isotopically resolved Raman spectra of C60

S. Guha, Jose Menendez, J. B. Page, G. B. Adams, G. S. Spencer, J. P. Lehman, P. Giannozzi, S. Baroni

Physics

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39 Scopus citations

Abstract

We present high-resolution Raman spectra of C60 molecules. The totally symmetric mode near 1470 cm-1 shows a fine structure which is almost exactly isomorphic with the mass spectrum of the molecule. We show that this surprising result can be explained in terms of isotopically induced frequency shifts and the unique icosahedral symmetry of the molecule. A comparison of predicted and observed isotope shifts provides a stringent test of vibrational theories for C60.

Original language	English (US)
Pages (from-to)	3359-3362
Number of pages	4
Journal	Physical Review Letters
Volume	72
Issue number	21
DOIs	https://doi.org/10.1103/PhysRevLett.72.3359
State	Published - 1994

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1103/PhysRevLett.72.3359

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title = "Isotopically resolved Raman spectra of C60",

abstract = "We present high-resolution Raman spectra of C60 molecules. The totally symmetric mode near 1470 cm-1 shows a fine structure which is almost exactly isomorphic with the mass spectrum of the molecule. We show that this surprising result can be explained in terms of isotopically induced frequency shifts and the unique icosahedral symmetry of the molecule. A comparison of predicted and observed isotope shifts provides a stringent test of vibrational theories for C60.",

author = "S. Guha and Jose Menendez and Page, {J. B.} and Adams, {G. B.} and Spencer, {G. S.} and Lehman, {J. P.} and P. Giannozzi and S. Baroni",

year = "1994",

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T1 - Isotopically resolved Raman spectra of C60

AU - Guha, S.

AU - Menendez, Jose

AU - Page, J. B.

AU - Adams, G. B.

AU - Spencer, G. S.

AU - Lehman, J. P.

AU - Giannozzi, P.

AU - Baroni, S.

PY - 1994

Y1 - 1994

N2 - We present high-resolution Raman spectra of C60 molecules. The totally symmetric mode near 1470 cm-1 shows a fine structure which is almost exactly isomorphic with the mass spectrum of the molecule. We show that this surprising result can be explained in terms of isotopically induced frequency shifts and the unique icosahedral symmetry of the molecule. A comparison of predicted and observed isotope shifts provides a stringent test of vibrational theories for C60.

AB - We present high-resolution Raman spectra of C60 molecules. The totally symmetric mode near 1470 cm-1 shows a fine structure which is almost exactly isomorphic with the mass spectrum of the molecule. We show that this surprising result can be explained in terms of isotopically induced frequency shifts and the unique icosahedral symmetry of the molecule. A comparison of predicted and observed isotope shifts provides a stringent test of vibrational theories for C60.

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U2 - 10.1103/PhysRevLett.72.3359

DO - 10.1103/PhysRevLett.72.3359

M3 - Article

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JO - Physical Review Letters

JF - Physical Review Letters

IS - 21

ER -

Isotopically resolved Raman spectra of C60

Abstract

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