TY - JOUR
T1 - Hydrothermal liquefaction of green microalga Kirchneriella sp. under sub- and super-critical water conditions
AU - Dandamudi, Kodanda Phani Raj
AU - Muppaneni, Tapaswy
AU - Markovski, Jasmina S.
AU - Lammers, Peter
AU - Deng, Shuguang
N1 - Publisher Copyright:
© 2018
PY - 2019/1
Y1 - 2019/1
N2 - Hydrothermal liquefaction (HTL) is one of the promising and reliable thermochemical conversion processes capable of converting wet biomass feedstock into renewable bio-oils. In this study, microalga Kirchneriella sp. was liquefied under hydrothermal conditions in a stainless-steel batch reactor. Various process parameters such as reaction temperature, pressure, biomass solid loading, and reaction duration were varied from 200 to 375 °C, 9–25 MPa, 10–20%, and 15–60 min, respectively. A one-factor-at-a-time approach was employed, and comprehensive experimental runs were further performed at 10% solid loading and a reaction time of 30 min. The maximum bio-crude yield (45.5%) was obtained at 300 °C, 9 MPa, with 10% solid loading and 30 min reaction duration. Fresh algal biomass, bio-oil and biochar samples were characterized by the ultimate and proximate analyses. The bio-oil and bio-char samples obtained at 300 °C, 9 MPa, with 10% solid loading and 30 min reaction duration have a higher heating value of 37.52 and 23.48 MJ kg−1, respectively. The HTL aqueous phase was analyzed for potential co-products by spectrophotometric techniques and is rich in soluble carbohydrates, dissolved ammoniacal nitrogen and phosphates. The metal impurities in the algae, bio-oil, and biochar were identified by ICP-OES where algae and biochar contain a large proportion of phosphorous and magnesium.
AB - Hydrothermal liquefaction (HTL) is one of the promising and reliable thermochemical conversion processes capable of converting wet biomass feedstock into renewable bio-oils. In this study, microalga Kirchneriella sp. was liquefied under hydrothermal conditions in a stainless-steel batch reactor. Various process parameters such as reaction temperature, pressure, biomass solid loading, and reaction duration were varied from 200 to 375 °C, 9–25 MPa, 10–20%, and 15–60 min, respectively. A one-factor-at-a-time approach was employed, and comprehensive experimental runs were further performed at 10% solid loading and a reaction time of 30 min. The maximum bio-crude yield (45.5%) was obtained at 300 °C, 9 MPa, with 10% solid loading and 30 min reaction duration. Fresh algal biomass, bio-oil and biochar samples were characterized by the ultimate and proximate analyses. The bio-oil and bio-char samples obtained at 300 °C, 9 MPa, with 10% solid loading and 30 min reaction duration have a higher heating value of 37.52 and 23.48 MJ kg−1, respectively. The HTL aqueous phase was analyzed for potential co-products by spectrophotometric techniques and is rich in soluble carbohydrates, dissolved ammoniacal nitrogen and phosphates. The metal impurities in the algae, bio-oil, and biochar were identified by ICP-OES where algae and biochar contain a large proportion of phosphorous and magnesium.
KW - Algae
KW - Biocrude oil
KW - Elemental analysis
KW - Energy
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U2 - 10.1016/j.biombioe.2018.11.021
DO - 10.1016/j.biombioe.2018.11.021
M3 - Article
AN - SCOPUS:85057306187
SN - 0961-9534
VL - 120
SP - 224
EP - 228
JO - Biomass and Bioenergy
JF - Biomass and Bioenergy
ER -