Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Raja Pal; Joseph A. Laureanti; Thomas L. Groy; Anne Jones; Ryan Trovitch

doi:10.1039/c6cc04946j

Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Raja Pal, Joseph A. Laureanti, Thomas L. Groy, Anne Jones, Ryan Trovitch

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

In 5.0 M H₂O/acetonitrile, [(^Ph2PPrPDI)MoO][PF₆]₂ produces H₂ with 96% Faradaic efficiency at -2.5 V vs. Fc^+/0 and a rate of 55 s^-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (^Ph2PPrPDI)MoO, shed light on the H₂ evolution mechanism.

Original language	English (US)
Pages (from-to)	11555-11558
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	77
DOIs	https://doi.org/10.1039/c6cc04946j
State	Published - 2016

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c6cc04946j

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title = "Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst",

abstract = "In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.",

author = "Raja Pal and Laureanti, {Joseph A.} and Groy, {Thomas L.} and Anne Jones and Ryan Trovitch",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6cc04946j",

language = "English (US)",

volume = "52",

pages = "11555--11558",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

AU - Pal, Raja

AU - Laureanti, Joseph A.

AU - Groy, Thomas L.

AU - Jones, Anne

AU - Trovitch, Ryan

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.

AB - In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.

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U2 - 10.1039/c6cc04946j

DO - 10.1039/c6cc04946j

M3 - Article

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VL - 52

SP - 11555

EP - 11558

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Abstract

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CCDC 1480115: Experimental Crystal Structure Determination

CCDC 1480114: Experimental Crystal Structure Determination

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Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1480115: Experimental Crystal Structure Determination

CCDC 1480114: Experimental Crystal Structure Determination

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