Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene: metal-carbon interaction

Yang Lou; Jia Xu; Honglu Wu; Jingyue Liu

doi:10.1039/C8CC07430E

Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene: metal-carbon interaction

Yang Lou, Jia Xu, Honglu Wu, Jingyue Liu

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Constructing Pd-C bond between Pd particles and defective hollow nanocarbons (h-NCs) not only enables facile H₂ dissociation but also diffusion of the dissociated H species, which makes the Pd/h-NC highly active with a TOF of 21 845 h⁻¹ (>80 times higher than that of the best catalyst in literature), selective (97%), and stable (4 cycles) for selective hydrogenation of 3-nitrostyrene to 3-ethylnitrobenze.

Original language	English (US)
Pages (from-to)	13248-13251
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	94
DOIs	https://doi.org/10.1039/C8CC07430E
State	Published - 2018

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Constructing Pd-C bond between Pd particles and defective hollow nanocarbons (h-NCs) not only enables facile H2 dissociation but also diffusion of the dissociated H species, which makes the Pd/h-NC highly active with a TOF of 21 845 h−1 (>80 times higher than that of the best catalyst in literature), selective (97%), and stable (4 cycles) for selective hydrogenation of 3-nitrostyrene to 3-ethylnitrobenze.",

author = "Yang Lou and Jia Xu and Honglu Wu and Jingyue Liu",

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doi = "10.1039/C8CC07430E",

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pages = "13248--13251",

journal = "Chemical Communications",

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T1 - Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene

T2 - metal-carbon interaction

AU - Lou, Yang

AU - Xu, Jia

AU - Wu, Honglu

AU - Liu, Jingyue

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018

Y1 - 2018

N2 - Constructing Pd-C bond between Pd particles and defective hollow nanocarbons (h-NCs) not only enables facile H2 dissociation but also diffusion of the dissociated H species, which makes the Pd/h-NC highly active with a TOF of 21 845 h−1 (>80 times higher than that of the best catalyst in literature), selective (97%), and stable (4 cycles) for selective hydrogenation of 3-nitrostyrene to 3-ethylnitrobenze.

AB - Constructing Pd-C bond between Pd particles and defective hollow nanocarbons (h-NCs) not only enables facile H2 dissociation but also diffusion of the dissociated H species, which makes the Pd/h-NC highly active with a TOF of 21 845 h−1 (>80 times higher than that of the best catalyst in literature), selective (97%), and stable (4 cycles) for selective hydrogenation of 3-nitrostyrene to 3-ethylnitrobenze.

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SP - 13248

EP - 13251

JO - Chemical Communications

JF - Chemical Communications

IS - 94

ER -

Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene: metal-carbon interaction

Abstract

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