Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra

Heng Wang; Kun Wang; Yaping Xu; Wu Wang; Shaohua Chen; Matthew Hart; Lukasz Wojtas; Li Peng Zhou; Lin Gan; Xuzhou Yan; Yiming Li; Juhoon Lee; Xian Sheng Ke; Xu Qing Wang; Chang Wei Zhang; Shasha Zhou; Tianyou Zhai; Hai Bo Yang; Ming Wang; Jiaqing He; Qing Fu Sun; Bingqian Xu; Yang Jiao; Peter J. Stang; Jonathan L. Sessler; Xiaopeng Li

doi:10.1021/jacs.1c00625

Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra

Heng Wang, Kun Wang, Yaping Xu, Wu Wang, Shaohua Chen, Matthew Hart, Lukasz Wojtas, Li Peng Zhou, Lin Gan, Xuzhou Yan, Yiming Li, Juhoon Lee, Xian Sheng Ke, Xu Qing Wang, Chang Wei Zhang, Shasha Zhou, Tianyou Zhai, Hai Bo Yang, Ming Wang, Jiaqing HeQing Fu Sun, Bingqian Xu, Yang Jiao, Peter J. Stang, Jonathan L. Sessler, Xiaopeng Li

Engineering, Ira A. Fulton Schools of (IAFSE)

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Parastichy, the spiral arrangement of plant organs, is an example of the long-range apparent order seen in biological systems. These ordered arrangements provide scientists with both an aesthetic challenge and a mathematical inspiration. Synthetic efforts to replicate the regularity of parastichy may allow for molecular-scale control over particle arrangement processes. Here we report the packing of a supramolecular truncated cuboctahedron (TCO) into double-helical (DH) nanowires on a graphite surface with a non-natural parastichy pattern ascribed to the symmetry of the TCOs and interactions between TCOs. Such a study is expected to advance our understanding of the design inputs needed to create complex, but precisely controlled, hierarchical materials. It is also one of the few reported helical packing structures based on Platonic or Archimedean solids since the discovery of the Boerdijk-Coxeter helix. As such, it may provide experimental support for studies of packing theory at the molecular level.

Original language	English (US)
Pages (from-to)	5826-5835
Number of pages	10
Journal	Journal of the American Chemical Society
Volume	143
Issue number	15
DOIs	https://doi.org/10.1021/jacs.1c00625
State	Published - Apr 21 2021

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.1c00625

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Wang, H., Wang, K., Xu, Y., Wang, W., Chen, S., Hart, M., Wojtas, L., Zhou, L. P., Gan, L., Yan, X., Li, Y., Lee, J., Ke, X. S., Wang, X. Q., Zhang, C. W., Zhou, S., Zhai, T., Yang, H. B., Wang, M., ... Li, X. (2021). Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra. Journal of the American Chemical Society, 143(15), 5826-5835. https://doi.org/10.1021/jacs.1c00625

Wang, H, Wang, K, Xu, Y, Wang, W, Chen, S, Hart, M, Wojtas, L, Zhou, LP, Gan, L, Yan, X, Li, Y, Lee, J, Ke, XS, Wang, XQ, Zhang, CW, Zhou, S, Zhai, T, Yang, HB, Wang, M, He, J, Sun, QF, Xu, B, Jiao, Y, Stang, PJ, Sessler, JL & Li, X 2021, 'Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra', Journal of the American Chemical Society, vol. 143, no. 15, pp. 5826-5835. https://doi.org/10.1021/jacs.1c00625

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title = "Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra",

abstract = "Parastichy, the spiral arrangement of plant organs, is an example of the long-range apparent order seen in biological systems. These ordered arrangements provide scientists with both an aesthetic challenge and a mathematical inspiration. Synthetic efforts to replicate the regularity of parastichy may allow for molecular-scale control over particle arrangement processes. Here we report the packing of a supramolecular truncated cuboctahedron (TCO) into double-helical (DH) nanowires on a graphite surface with a non-natural parastichy pattern ascribed to the symmetry of the TCOs and interactions between TCOs. Such a study is expected to advance our understanding of the design inputs needed to create complex, but precisely controlled, hierarchical materials. It is also one of the few reported helical packing structures based on Platonic or Archimedean solids since the discovery of the Boerdijk-Coxeter helix. As such, it may provide experimental support for studies of packing theory at the molecular level.",

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AU - Zhai, Tianyou

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AU - Wang, Ming

AU - He, Jiaqing

AU - Sun, Qing Fu

AU - Xu, Bingqian

AU - Jiao, Yang

AU - Stang, Peter J.

AU - Sessler, Jonathan L.

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Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra

Abstract

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CCDC 2056916: Experimental Crystal Structure Determination

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Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra

Abstract

ASJC Scopus subject areas

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CCDC 2056916: Experimental Crystal Structure Determination

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