TY - JOUR
T1 - Fog chemistry at three sites in Norway
AU - Wang, Youliang
AU - Zhang, Jinwei
AU - Marcotte, Aurelie R.
AU - Karl, Matthias
AU - Dye, Christian
AU - Herckes, Pierre
N1 - Funding Information:
The authors also acknowledge funding from the US National Science Foundation grant AGS 0847710 . Special thanks to Are Bäcklund, Jan H. Wasseng, Elisabeth Basteson, Dorothea Schulze (all NILU) for maintenance of the fog measurement infrastructure.
Funding Information:
Part of this work has been performed in the framework of the technology qualification of amines for the CO 2 Capture Mongstad Project (CCM) (Contract no. 4502452105-2) funded by the Norwegian Government through Statoil Petroleum AS and Gassnova SF.
Publisher Copyright:
© 2014 Elsevier B.V.
Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 2015/1/1
Y1 - 2015/1/1
N2 - Fog composition was investigated at three sites in Norway, one in suburban Oslo and two coastal sites in the area of the Mongstad refinery. Overall fog frequency during the study periods was low. Fog pH was around 5 with slightly lower values at Hakadal, the suburban site, compared to the coastal sites, which were slightly above 5. Major ions at the coastal sites were sodium and chloride consistent with the marine environment. The ion chemistry at the suburban site was dominated by ammonium, sulfate and nitrate, consistent with fogs in anthropogenically impacted environments. Overall concentrations of major ions were very low, orders of magnitude lower than those in polluted urban fogs. Organic matter concentrations were also low (<. 3. mgC/L) consistent with limited anthropogenic impact and little biogenic activity in the winter months. Selected amine concentrations were determined and ranged from nanomolar concentrations for ethylamines to several hundred nanomolar concentrations for dimethylamine, the most abundant amine investigated. While N-nitrosodimehylamine was detected in fog, the concentrations were very low in the fogs.
AB - Fog composition was investigated at three sites in Norway, one in suburban Oslo and two coastal sites in the area of the Mongstad refinery. Overall fog frequency during the study periods was low. Fog pH was around 5 with slightly lower values at Hakadal, the suburban site, compared to the coastal sites, which were slightly above 5. Major ions at the coastal sites were sodium and chloride consistent with the marine environment. The ion chemistry at the suburban site was dominated by ammonium, sulfate and nitrate, consistent with fogs in anthropogenically impacted environments. Overall concentrations of major ions were very low, orders of magnitude lower than those in polluted urban fogs. Organic matter concentrations were also low (<. 3. mgC/L) consistent with limited anthropogenic impact and little biogenic activity in the winter months. Selected amine concentrations were determined and ranged from nanomolar concentrations for ethylamines to several hundred nanomolar concentrations for dimethylamine, the most abundant amine investigated. While N-nitrosodimehylamine was detected in fog, the concentrations were very low in the fogs.
KW - Amines
KW - Cloud
KW - Fog
KW - Nitrosamines
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U2 - 10.1016/j.atmosres.2014.04.016
DO - 10.1016/j.atmosres.2014.04.016
M3 - Article
AN - SCOPUS:84910082570
SN - 0169-8095
VL - 151
SP - 72
EP - 81
JO - Atmospheric Research
JF - Atmospheric Research
ER -