Fluctuations in Energy in Completely Open Small Systems

Terrell L. Hill; Ralph Chamberlin

doi:10.1021/nl020295+

Fluctuations in Energy in Completely Open Small Systems

Terrell L. Hill, Ralph Chamberlin

Physics

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

General equations are derived for fluctuations in energy in small completely open μ, p, T and μ, T or μ₁, μ₂, T (incompressible) systems. Four examples are considered. As expected, the fluctuations are unusually large because there are no restraints on the size of the system. Also, fluctuations in N and V or in N₁ and N₂ contribute indirectly to the fluctuations in E.

Original language	English (US)
Pages (from-to)	609-613
Number of pages	5
Journal	Nano Letters
Volume	2
Issue number	6
DOIs	https://doi.org/10.1021/nl020295+
State	Published - Jun 2002

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

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10.1021/nl020295+

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abstract = "General equations are derived for fluctuations in energy in small completely open μ, p, T and μ, T or μ1, μ2, T (incompressible) systems. Four examples are considered. As expected, the fluctuations are unusually large because there are no restraints on the size of the system. Also, fluctuations in N and V or in N1 and N2 contribute indirectly to the fluctuations in E.",

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AB - General equations are derived for fluctuations in energy in small completely open μ, p, T and μ, T or μ1, μ2, T (incompressible) systems. Four examples are considered. As expected, the fluctuations are unusually large because there are no restraints on the size of the system. Also, fluctuations in N and V or in N1 and N2 contribute indirectly to the fluctuations in E.

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Fluctuations in Energy in Completely Open Small Systems

Abstract

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