Electron transfer accompanied by bond rupture

D. V. Matyushov; Y. A. Maletin

doi:10.1016/0301-0104(88)87130-1

Electron transfer accompanied by bond rupture

D. V. Matyushov, Y. A. Maletin

Research output: Contribution to journal › Article › peer-review

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Abstract

A theoretical model for inner-sphere electron transfer via a bridging metal ion is presented. The probability of electron transfer and the rate constant of the process were calculated in a semiclassical approximation by taking into account the simultaneous motion of the system along two reaction coordinates: environmental polarization change and rupturing metal-ligand bond elongation. The results of the calculations are (briefly) compared with experimental kinetic data.

Original language	English (US)
Pages (from-to)	325-334
Number of pages	10
Journal	Chemical Physics
Volume	127
Issue number	1-3
DOIs	https://doi.org/10.1016/0301-0104(88)87130-1
State	Published - Nov 15 1988
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0301-0104(88)87130-1

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title = "Electron transfer accompanied by bond rupture",

abstract = "A theoretical model for inner-sphere electron transfer via a bridging metal ion is presented. The probability of electron transfer and the rate constant of the process were calculated in a semiclassical approximation by taking into account the simultaneous motion of the system along two reaction coordinates: environmental polarization change and rupturing metal-ligand bond elongation. The results of the calculations are (briefly) compared with experimental kinetic data.",

author = "Matyushov, {D. V.} and Maletin, {Y. A.}",

year = "1988",

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AU - Matyushov, D. V.

AU - Maletin, Y. A.

PY - 1988/11/15

Y1 - 1988/11/15

N2 - A theoretical model for inner-sphere electron transfer via a bridging metal ion is presented. The probability of electron transfer and the rate constant of the process were calculated in a semiclassical approximation by taking into account the simultaneous motion of the system along two reaction coordinates: environmental polarization change and rupturing metal-ligand bond elongation. The results of the calculations are (briefly) compared with experimental kinetic data.

AB - A theoretical model for inner-sphere electron transfer via a bridging metal ion is presented. The probability of electron transfer and the rate constant of the process were calculated in a semiclassical approximation by taking into account the simultaneous motion of the system along two reaction coordinates: environmental polarization change and rupturing metal-ligand bond elongation. The results of the calculations are (briefly) compared with experimental kinetic data.

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U2 - 10.1016/0301-0104(88)87130-1

DO - 10.1016/0301-0104(88)87130-1

M3 - Article

AN - SCOPUS:0040552396

SN - 0301-0104

VL - 127

SP - 325

EP - 334

JO - Chemical Physics

JF - Chemical Physics

IS - 1-3

ER -

Electron transfer accompanied by bond rupture

Abstract

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