TY - JOUR
T1 - Electrical study of Schottky-barrier heights on atomically clean p-type InP(110) surfaces
AU - Newman, N.
AU - Van Schilfgaarde, M.
AU - Spicer, W. E.
PY - 1987/1/1
Y1 - 1987/1/1
N2 - We report here a systematic study of the electrical properties of a large number of metal (Ag, Cr, Cu, Au, Pd, Mn, Al, Ni) on p-type InP diodes. Schottky-barrier diodes were fabricated by in situ metal deposition on atomically clean InP(110) surfaces in ultrahigh vacuum. Schottky-barrier heights were determined from current-voltage (I-V) and capacitance-voltage (C-V) measurements. A small, but finite, range in barrier heights (0.760.98 eV) is found for the metalp-type InP systems investigated. When a comparison is made to our earlier work on n-type surfaces, we find that the interface Fermi level of n-type and p-type samples pins at the same position within the band gap for each of the metal InP systems studied. Our experimental results indicate that models that use metal-independent surface states (energy and density) and potential normalization conditions (i.e., natural band lineups) can predict the general trends in the interface Fermi-level pinning behavior. They cannot, however, successfully predict the details of this behavior to within measurement error. A theoretical method to determine the natural band lineups at the interface (using a scheme developed by Anderson) is presented within this context. Also investigated was the effect of air exposure on the electrical characteristics of diodes. For in situ I-V measurements, the metal semiconductor systems were characterized by a near-unity (1.031.10) ideality factor n. Upon exposure to air, a large increase in the current and ideality factor n was found for several (Cu, Au, Pd, Mn, Ni) metalp-type InP systems at all measured biases. A detailed investigation of the Pdp-type InP system indicated that the excess current pathway which results from exposure to air is at the periphery and can be eliminated by mesa etching.
AB - We report here a systematic study of the electrical properties of a large number of metal (Ag, Cr, Cu, Au, Pd, Mn, Al, Ni) on p-type InP diodes. Schottky-barrier diodes were fabricated by in situ metal deposition on atomically clean InP(110) surfaces in ultrahigh vacuum. Schottky-barrier heights were determined from current-voltage (I-V) and capacitance-voltage (C-V) measurements. A small, but finite, range in barrier heights (0.760.98 eV) is found for the metalp-type InP systems investigated. When a comparison is made to our earlier work on n-type surfaces, we find that the interface Fermi level of n-type and p-type samples pins at the same position within the band gap for each of the metal InP systems studied. Our experimental results indicate that models that use metal-independent surface states (energy and density) and potential normalization conditions (i.e., natural band lineups) can predict the general trends in the interface Fermi-level pinning behavior. They cannot, however, successfully predict the details of this behavior to within measurement error. A theoretical method to determine the natural band lineups at the interface (using a scheme developed by Anderson) is presented within this context. Also investigated was the effect of air exposure on the electrical characteristics of diodes. For in situ I-V measurements, the metal semiconductor systems were characterized by a near-unity (1.031.10) ideality factor n. Upon exposure to air, a large increase in the current and ideality factor n was found for several (Cu, Au, Pd, Mn, Ni) metalp-type InP systems at all measured biases. A detailed investigation of the Pdp-type InP system indicated that the excess current pathway which results from exposure to air is at the periphery and can be eliminated by mesa etching.
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U2 - 10.1103/PhysRevB.35.6298
DO - 10.1103/PhysRevB.35.6298
M3 - Article
AN - SCOPUS:0011119238
SN - 0163-1829
VL - 35
SP - 6298
EP - 6304
JO - Physical Review B
JF - Physical Review B
IS - 12
ER -