@article{7f56108c9029423a92548616af582cb2,
title = "Ehrenfest+R dynamics. II. A semiclassical QED framework for Raman scattering",
abstract = "In Paper I [Chen et al., J. Chem. Phys. 150, 044102 (2019)], we introduced Ehrenfest+R dynamics for a two-level system and showed how spontaneous emission can be heuristically included such that, after averaging over an ensemble of Ehrenfest+R trajectories, one can recover both coherent and incoherent electromagnetic fields. In the present paper, we now show that Ehrenfest+R dynamics can also correctly describe Raman scattering, whose features are completely absent from standard Ehrenfest dynamics. Ehrenfest+R dynamics appear to be quantitatively accurate both for resonant and off-resonant Raman signals, as compared with Kramers-Heisenberg-Dirac theory.",
author = "Chen, {Hsing Ta} and Li, {Tao E.} and Maxim Sukharev and Abraham Nitzan and Subotnik, {Joseph E.}",
note = "Funding Information: This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award No. DE-SC0019397. The research of A.N. was supported by the Israel-U.S. Binational Science Foundation, the German Research Foundation (No. DFG TH 820/11-1), the U.S. National Science Foundation (Grant No. CHE1665291), and the University of Pennsylvania. M.S. was grateful to the financial support provided by the Air Force Office of Scientific Research under Grant No. FA9550-15-1-0189 and Binational Science Foundation under Grant No. 2014113. Publisher Copyright: {\textcopyright} 2019 Author(s).",
year = "2019",
month = jan,
day = "28",
doi = "10.1063/1.5057366",
language = "English (US)",
volume = "150",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "4",
}