Competing interactions among supramolecular structures on surfaces

M. Sayar; F. J. Solis; M. Olvera De La Cruz; S. I. Stupp

doi:10.1021/ma000734w

Competing interactions among supramolecular structures on surfaces

M. Sayar, F. J. Solis, M. Olvera De La Cruz, S. I. Stupp

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The nanocentrosymmetric structures of copolymers are analyzed by field continuous models. Results reveal that the ground state of a system composed of dipolar supermolecular aggregates that interact with a surface is a periodic domain structure with a net macroscopic polarization. The Monte Carlo simulations for some hexagonal lattices and smectic-A structures also give stripe structures with a similar λ dependence on film thickness.

Original language	English (US)
Pages (from-to)	7226-7228
Number of pages	3
Journal	Macromolecules
Volume	33
Issue number	20
DOIs	https://doi.org/10.1021/ma000734w
State	Published - Oct 3 2000
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma000734w

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title = "Competing interactions among supramolecular structures on surfaces",

abstract = "The nanocentrosymmetric structures of copolymers are analyzed by field continuous models. Results reveal that the ground state of a system composed of dipolar supermolecular aggregates that interact with a surface is a periodic domain structure with a net macroscopic polarization. The Monte Carlo simulations for some hexagonal lattices and smectic-A structures also give stripe structures with a similar λ dependence on film thickness.",

author = "M. Sayar and Solis, {F. J.} and {Olvera De La Cruz}, M. and Stupp, {S. I.}",

year = "2000",

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T1 - Competing interactions among supramolecular structures on surfaces

AU - Sayar, M.

AU - Solis, F. J.

AU - Olvera De La Cruz, M.

AU - Stupp, S. I.

PY - 2000/10/3

Y1 - 2000/10/3

N2 - The nanocentrosymmetric structures of copolymers are analyzed by field continuous models. Results reveal that the ground state of a system composed of dipolar supermolecular aggregates that interact with a surface is a periodic domain structure with a net macroscopic polarization. The Monte Carlo simulations for some hexagonal lattices and smectic-A structures also give stripe structures with a similar λ dependence on film thickness.

AB - The nanocentrosymmetric structures of copolymers are analyzed by field continuous models. Results reveal that the ground state of a system composed of dipolar supermolecular aggregates that interact with a surface is a periodic domain structure with a net macroscopic polarization. The Monte Carlo simulations for some hexagonal lattices and smectic-A structures also give stripe structures with a similar λ dependence on film thickness.

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DO - 10.1021/ma000734w

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JO - Macromolecules

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Competing interactions among supramolecular structures on surfaces

Abstract

ASJC Scopus subject areas

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