An emulsion technique for the study of marginal glass formation in molecular liquids

D. R. MacFarlane; C. A. Angell

doi:10.1021/j100208a003

An emulsion technique for the study of marginal glass formation in molecular liquids

D. R. MacFarlane, C. A. Angell

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Abstract

An emulsion has been used to discourage crystallization and permit the observation of a glass transition in molecular liquids such as chlorobenzene which were not previously thought to be glass forming. Glass-forming abilities in such marginal cases appear to be correlated by an extension of the Cohen-Turnbull T_B/T_m > 2 rule. Transparent, repeatedly vitrefiable, microemulsions have also been made.

Original language	English (US)
Pages (from-to)	1927-1930
Number of pages	4
Journal	Journal of physical chemistry
Volume	86
Issue number	11
DOIs	https://doi.org/10.1021/j100208a003
State	Published - Jan 1 1982
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

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10.1021/j100208a003

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abstract = "An emulsion has been used to discourage crystallization and permit the observation of a glass transition in molecular liquids such as chlorobenzene which were not previously thought to be glass forming. Glass-forming abilities in such marginal cases appear to be correlated by an extension of the Cohen-Turnbull TB/Tm > 2 rule. Transparent, repeatedly vitrefiable, microemulsions have also been made.",

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AB - An emulsion has been used to discourage crystallization and permit the observation of a glass transition in molecular liquids such as chlorobenzene which were not previously thought to be glass forming. Glass-forming abilities in such marginal cases appear to be correlated by an extension of the Cohen-Turnbull TB/Tm > 2 rule. Transparent, repeatedly vitrefiable, microemulsions have also been made.

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An emulsion technique for the study of marginal glass formation in molecular liquids

Abstract

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