TY - GEN
T1 - Ab initio and experimental studies of VOC interactions with ionic liquid (C4mimCl) surfaces
AU - Gao, Tingting
AU - Andino, Jean
PY - 2010/12/1
Y1 - 2010/12/1
N2 - Gas-phase sensors for the detection of alcohols are very important since these classes of compounds are widely used, including in the medical field, within the food industry, and the automotive fuel industry. The interactions between an ionic liquid and different kinds of VOC, e.g., methanol and ethane, were investigated through coupled computational chemistry and experimental techniques. The types of VOC included in this study were alcohols, aldehydes, a ketone, alkanes, alkenes, an alkyne, and an aromatic hydrocarbon. There were interactions between C4mimCl and alcohols. No new peaks were detected in the IR spectra after exposure of the C4mimCl to aldehydes, a ketone, an alkane, an alkene, an alkyne, or an aromatic hydrocarbon. In the IR region, C4mimCl selectively responded to alcohols. Thus, C4mimCl might be an ideal substrate for the development of selective gas-phase alcohol sensors. This is an abstract of a paper presented at the 103rd AWMA Annual Conference and Exhibition (Calgary, Alberta, Canada 6/22-25/2010).
AB - Gas-phase sensors for the detection of alcohols are very important since these classes of compounds are widely used, including in the medical field, within the food industry, and the automotive fuel industry. The interactions between an ionic liquid and different kinds of VOC, e.g., methanol and ethane, were investigated through coupled computational chemistry and experimental techniques. The types of VOC included in this study were alcohols, aldehydes, a ketone, alkanes, alkenes, an alkyne, and an aromatic hydrocarbon. There were interactions between C4mimCl and alcohols. No new peaks were detected in the IR spectra after exposure of the C4mimCl to aldehydes, a ketone, an alkane, an alkene, an alkyne, or an aromatic hydrocarbon. In the IR region, C4mimCl selectively responded to alcohols. Thus, C4mimCl might be an ideal substrate for the development of selective gas-phase alcohol sensors. This is an abstract of a paper presented at the 103rd AWMA Annual Conference and Exhibition (Calgary, Alberta, Canada 6/22-25/2010).
KW - Computational chemistry
KW - Interaction
KW - Ionic liquid
KW - Volatile organic compounds
UR - http://www.scopus.com/inward/record.url?scp=79956202784&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79956202784&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:79956202784
SN - 9781617820939
T3 - Proceedings of the Air and Waste Management Association's Annual Conference and Exhibition, AWMA
SP - 3392
EP - 3407
BT - 103rd Air and Waste Management Association Annual Conference and Exhibition 2010 - Manuscripts/Extended Abstracts
T2 - 103rd Air and Waste Management Association Annual Conference and Exhibition 2010
Y2 - 22 June 2010 through 25 June 2010
ER -