Abstract
We discovered a new CaGe2O5 polymorph in high-pressure experiments (above 8 GPa). The phase is orthorhombic, space group Pbam, with a = 7.306(2), b = 8.268(2), c = 5.714(1) Å, V = 345.2(1) Å3, and Z = 4. The new phase, which we call post-titanite CaGe2O5, is the high-pressure polymorph of titanite CaGe2O5. The structure of this new polymorph is based on a network of 5- and 6-coordinated Ge polyhedra and 8-coordinated Ca atoms. Following the germanate analog to silicate, post-titanite CaSi2O5 could be expected to form at high-pressure conditions and thus might exist in Earth's mantle.
Original language | English (US) |
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Pages (from-to) | 441-443 |
Number of pages | 3 |
Journal | American Mineralogist |
Volume | 92 |
Issue number | 2-3 |
DOIs | |
State | Published - Feb 1 2007 |
Keywords
- 5- and 6-coordinated Ge
- CaGeO polymorph
- Earth's mantle
- Post-titanite
ASJC Scopus subject areas
- Geophysics
- Geochemistry and Petrology