TY - JOUR
T1 - 3D Printing Carbonaceous Objects from Polyimide Pyrolysis
AU - Arrington, Clay B.
AU - Rau, Daniel A.
AU - Vandenbrande, Johanna A.
AU - Hegde, Maruti
AU - Williams, Christopher B.
AU - Long, Timothy E.
N1 - Funding Information:
The authors graciously acknowledge Honeywell National Security Campus for financial support. The authors thank the Macromolecular Innovation Institute at Virginia Tech for access to Raman spectroscopy.
Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/4/20
Y1 - 2021/4/20
N2 - Fully aromatic polyimides are amenable to efficient carbonization in thin two-dimensional (2D) films due to a complement of aromaticity and planarity of backbone repeating units. However, repeating unit rigidity traditionally imposes processing limitations, restricting many fully aromatic polyimides, e.g., pyromellitic dianhydride with 4,4′-oxidianiline (PMDA-ODA) polyimides, to a 2D form factor. Recently, research efforts in our laboratories enabled additive manufacturing of micron-scale resolution PMDA-ODA polyimide objects using vat photopolymerization (VP) and ultraviolet-assisted direct ink write (UV-DIW) following careful thermal postprocessing of the three-dimensional (3D) organogel precursors to 400 °C. Further thermal postprocessing of printed objects to 1000 °C induced pyrolysis of the PMDA-ODA objects to disordered carbon. The pyrolyzed objects retained excellent geometric resolution, and Raman spectroscopy displayed characteristic disordered (D) and graphitic (G) carbon bands. Scanning electron microscopy probed the cross-sectional homogeneity of the carbonized samples, revealing an absence of pore formation during carbonization. Likewise, impedance analysis of carbonized specimens indicated only a moderate decrease in conductivity compared to thin films that were pyrolyzed using an identical carbonization process. Facile pyrolysis of PMDA-ODA objects now enables the production of carbonaceous monoliths with complex and predictable three-dimensional geometries using commercially available starting materials.
AB - Fully aromatic polyimides are amenable to efficient carbonization in thin two-dimensional (2D) films due to a complement of aromaticity and planarity of backbone repeating units. However, repeating unit rigidity traditionally imposes processing limitations, restricting many fully aromatic polyimides, e.g., pyromellitic dianhydride with 4,4′-oxidianiline (PMDA-ODA) polyimides, to a 2D form factor. Recently, research efforts in our laboratories enabled additive manufacturing of micron-scale resolution PMDA-ODA polyimide objects using vat photopolymerization (VP) and ultraviolet-assisted direct ink write (UV-DIW) following careful thermal postprocessing of the three-dimensional (3D) organogel precursors to 400 °C. Further thermal postprocessing of printed objects to 1000 °C induced pyrolysis of the PMDA-ODA objects to disordered carbon. The pyrolyzed objects retained excellent geometric resolution, and Raman spectroscopy displayed characteristic disordered (D) and graphitic (G) carbon bands. Scanning electron microscopy probed the cross-sectional homogeneity of the carbonized samples, revealing an absence of pore formation during carbonization. Likewise, impedance analysis of carbonized specimens indicated only a moderate decrease in conductivity compared to thin films that were pyrolyzed using an identical carbonization process. Facile pyrolysis of PMDA-ODA objects now enables the production of carbonaceous monoliths with complex and predictable three-dimensional geometries using commercially available starting materials.
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U2 - 10.1021/acsmacrolett.1c00032
DO - 10.1021/acsmacrolett.1c00032
M3 - Article
C2 - 35549232
AN - SCOPUS:85103763053
SN - 2161-1653
VL - 10
SP - 412
EP - 418
JO - ACS Macro Letters
JF - ACS Macro Letters
IS - 4
ER -