TY - JOUR
T1 - 3D printing aqueous Ti3C2Tx inks for MXene-based energy devices
AU - Fagade, Mofetoluwa
AU - Patil, Dhanush
AU - Thummalapalli, Sri Vaishnavi
AU - Jambhulkar, Sayli
AU - Ravichandran, Dharneedar
AU - Kannan, Arunachala M.
AU - Song, Kenan
N1 - Publisher Copyright:
© 2023 RSC.
PY - 2023/7/27
Y1 - 2023/7/27
N2 - The miniaturization of microenvironments and increasing demands on modern-day electronics have reinvigorated the search for new candidates to meet these needs. The MXene (Mn+1XnTx) family has been seen as the next major player in the field of microelectronics due to the unique combination of superior properties. Incorporating microelectronics in micropatterned structures via simple, cost-efficient processing also increases the possibilities of using them in smart devices and microsystems. This short communication reports the nanoparticle synthesis, suspension processing, and 3D printing of a titanium carbide (Ti3AlC2)-based MXene, with the derivation from its elemental powders. More importantly, the in situ etching method was employed to create a multi-layered MXene (Ti3C2Tx), showing high efficiency in generating delaminated Ti3C2Tx nanosheets. Afterward, water-based Ti3C2Tx inks were examined in varying (i.e., 30 mg mL−1, 50 mg mL−1, 100 mg mL−1, and 200 mg mL−1) concentrations for optimized rheologies. An ink-writing-based 3D printing method was then used for micropatterning MXene thin-layers on glass or polymer-coated substrates, demonstrating anisotropic electrical properties over varying strain and energy storage capabilities and showing enormous potential for 3D printable devices.
AB - The miniaturization of microenvironments and increasing demands on modern-day electronics have reinvigorated the search for new candidates to meet these needs. The MXene (Mn+1XnTx) family has been seen as the next major player in the field of microelectronics due to the unique combination of superior properties. Incorporating microelectronics in micropatterned structures via simple, cost-efficient processing also increases the possibilities of using them in smart devices and microsystems. This short communication reports the nanoparticle synthesis, suspension processing, and 3D printing of a titanium carbide (Ti3AlC2)-based MXene, with the derivation from its elemental powders. More importantly, the in situ etching method was employed to create a multi-layered MXene (Ti3C2Tx), showing high efficiency in generating delaminated Ti3C2Tx nanosheets. Afterward, water-based Ti3C2Tx inks were examined in varying (i.e., 30 mg mL−1, 50 mg mL−1, 100 mg mL−1, and 200 mg mL−1) concentrations for optimized rheologies. An ink-writing-based 3D printing method was then used for micropatterning MXene thin-layers on glass or polymer-coated substrates, demonstrating anisotropic electrical properties over varying strain and energy storage capabilities and showing enormous potential for 3D printable devices.
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U2 - 10.1039/d3ma00096f
DO - 10.1039/d3ma00096f
M3 - Article
AN - SCOPUS:85167509318
SN - 2633-5409
VL - 4
SP - 4103
EP - 4109
JO - Materials Advances
JF - Materials Advances
IS - 18
ER -