Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh; Thomas L. Groy; Amanda C. Bowman; Ryan Trovitch

doi:10.1039/c5cc09167e

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh, Thomas L. Groy, Amanda C. Bowman, Ryan Trovitch

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Reduction of 6-coordinate (^Ph2PPrDI)FeBr₂ under N₂ results in formation of the terminal dinitrogen complex, (^Ph2PPrDI)FeN₂. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ⁵-P,N,N,C_γ,P-^Ph2PPrDI^PrPPh)Fe]₂. Mechanistic possibilities for this transformation are discussed.

Original language	English (US)
Pages (from-to)	4553-4556
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	24
DOIs	https://doi.org/10.1039/c5cc09167e
State	Published - 2016

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc09167e

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title = "Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex",

abstract = "Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.",

author = "Chandrani Ghosh and Groy, {Thomas L.} and Bowman, {Amanda C.} and Ryan Trovitch",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c5cc09167e",

language = "English (US)",

volume = "52",

pages = "4553--4556",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "24",

}

TY - JOUR

T1 - Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

AU - Ghosh, Chandrani

AU - Groy, Thomas L.

AU - Bowman, Amanda C.

AU - Trovitch, Ryan

PY - 2016

Y1 - 2016

N2 - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

AB - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

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UR - http://www.scopus.com/inward/citedby.url?scp=84961285238&partnerID=8YFLogxK

U2 - 10.1039/c5cc09167e

DO - 10.1039/c5cc09167e

M3 - Article

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SN - 1359-7345

VL - 52

SP - 4553

EP - 4556

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Abstract

ASJC Scopus subject areas

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CCDC 1420990: Experimental Crystal Structure Determination

CCDC 1420991: Experimental Crystal Structure Determination

CCDC 1420992: Experimental Crystal Structure Determination

Cite this

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1420990: Experimental Crystal Structure Determination

CCDC 1420991: Experimental Crystal Structure Determination

CCDC 1420992: Experimental Crystal Structure Determination

Cite this