The Effect of Nitrogen on the Dihedral Angle Between Fe−Ni Melt and Ringwoodite: Implications for the Nitrogen Deficit in the Bulk Silicate Earth

Nitrogen (N) is extremely depleted in the bulk silicate Earth (BSE). However, whether the silicate magma ocean was as N-poor as the present-day BSE is unknown. We performed multi-anvil experiments at 20 GPa and 1,673−2,073 K to determine the dihedral angle of Fe−Ni−N alloy melt in ringwoodite matrix to investigate whether percolation of Fe-rich alloy melt in the solid mantle can explain N depletion in the BSE. The dihedral angles ranged from 112° to 137°, surpassing the wetting boundary. Our experiments suggest that N removal from the mantle by percolation of Fe-rich alloy melt to the Earth's core is unlikely. Therefore, besides N loss to space during planetesimal and planetary differentiation, as well as its segregation into the Earth core, the stranded Fe-rich metal in the deep mantle could be a hidden N reservoir, contributing to the anomalous depletion of N in the observable BSE.