Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework

Venkata S.Pavan K. Neti; Xiaofei Wu; Shuguang Deng; Luis Echegoyen

doi:10.1039/c3ce40706c

Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework

Venkata S.Pavan K. Neti, Xiaofei Wu, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (S_BET = 1315 m ² g^-1), and can store up to 0.8 wt% of H₂ at 77 K and 1 bar and 0.6 wt% of CH₄ at 298 K and 1 bar.

Original language	English (US)
Pages (from-to)	6892-6895
Number of pages	4
Journal	CrystEngComm
Volume	15
Issue number	35
DOIs	https://doi.org/10.1039/c3ce40706c
State	Published - Sep 21 2013
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (SBET = 1315 m 2 g-1), and can store up to 0.8 wt% of H2 at 77 K and 1 bar and 0.6 wt% of CH4 at 298 K and 1 bar.",

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AU - Neti, Venkata S.Pavan K.

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AU - Deng, Shuguang

AU - Echegoyen, Luis

PY - 2013/9/21

Y1 - 2013/9/21

N2 - A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (SBET = 1315 m 2 g-1), and can store up to 0.8 wt% of H2 at 77 K and 1 bar and 0.6 wt% of CH4 at 298 K and 1 bar.

AB - A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (SBET = 1315 m 2 g-1), and can store up to 0.8 wt% of H2 at 77 K and 1 bar and 0.6 wt% of CH4 at 298 K and 1 bar.

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Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework

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