Optimization of [Bmim][HSO4]-Catalyzed Transesterification of Camelina Oil

Huan Li; Tian Ma; Zhensheng Shen; An Li; Jie Yang; Dong Xiang; Jiuyi Liu; Shuguang Deng; Yingqiang Sun

doi:10.1002/ceat.201900477

Optimization of [Bmim][HSO₄]-Catalyzed Transesterification of Camelina Oil

Huan Li
, Tian Ma
, Zhensheng Shen
, An Li
, Jie Yang
, Dong Xiang
, Jiuyi Liu
, Shuguang Deng
, Yingqiang Sun

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO₄]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, M_methanol:M_{Camelina oil}, and M_[Bmim][HSO4]:M_{Camelina oil} on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO₄] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.

Original language	English (US)
Pages (from-to)	403-411
Number of pages	9
Journal	Chemical Engineering and Technology
Volume	43
Issue number	3
DOIs	https://doi.org/10.1002/ceat.201900477
State	Published - Mar 1 2020

Keywords

Camelina oil
Ionic liquids
Transesterification
[Bmim][HSO]

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

Access to Document

10.1002/ceat.201900477

Cite this

@article{0351babefcc446fc9ea2a763a86075fb,

title = "Optimization of [Bmim][HSO4]-Catalyzed Transesterification of Camelina Oil",

abstract = "1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO4]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, Mmethanol:MCamelina oil, and M[Bmim][HSO4]:MCamelina oil on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO4] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.",

keywords = "Camelina oil, Ionic liquids, Transesterification, [Bmim][HSO]",

author = "Huan Li and Tian Ma and Zhensheng Shen and An Li and Jie Yang and Dong Xiang and Jiuyi Liu and Shuguang Deng and Yingqiang Sun",

note = "Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2020",

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doi = "10.1002/ceat.201900477",

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T1 - Optimization of [Bmim][HSO4]-Catalyzed Transesterification of Camelina Oil

AU - Li, Huan

AU - Ma, Tian

AU - Shen, Zhensheng

AU - Li, An

AU - Yang, Jie

AU - Xiang, Dong

AU - Liu, Jiuyi

AU - Deng, Shuguang

AU - Sun, Yingqiang

PY - 2020/3/1

Y1 - 2020/3/1

N2 - 1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO4]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, Mmethanol:MCamelina oil, and M[Bmim][HSO4]:MCamelina oil on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO4] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.

AB - 1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO4]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, Mmethanol:MCamelina oil, and M[Bmim][HSO4]:MCamelina oil on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO4] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.

KW - Camelina oil

KW - Ionic liquids

KW - Transesterification

KW - [Bmim][HSO]

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