TY - JOUR
T1 - On the uncertain distinction between fast landscape exploration and second amorphous phase (ideal glass) interpretations of the ultrastable glass phenomenon
AU - Angell, Charles
N1 - Funding Information:
We acknowledge the support of the NSF Chemistry Division under grant no. CHE 12-13265 . This MS is based on a talk invited for the Symposium on Ultrastable Glasses at the 7th IDMRS conference, Barcelona 2013.
Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.
Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 2015/1/1
Y1 - 2015/1/1
N2 - This paper is written as a challenge to the ultrastable glass community to distinguish phenomenologically between the fast landscape searching scenario under discussion in the ultrastable glass community, and the alternative scenario in which the material in the ultrastable state is actually an attempted realization of the low temperature ideal glass phase of the system that can be reached in some systems, like ST2 water and amorphous silicon, and model systems like the attractive Jagla model, by a first order thermodynamic transition. These are special in that they exhibit first order phase transitions to the ground state that are accessible above the normal Tg of the high temperature phase - and in consequence exhibit vanishingly small excess entropies over crystal, and none of the "ubiquitous" glassy state cryogenic anomalies. In particular we show how, near a liquid-liquid critical point, the diffusivity can decrease arbitrarily rapidly over several orders of magnitude and that a growth front transformation from ultraslow phase to normal viscous liquid will be very difficult to distinguish from nucleation and growth of a new phase of different mobility.
AB - This paper is written as a challenge to the ultrastable glass community to distinguish phenomenologically between the fast landscape searching scenario under discussion in the ultrastable glass community, and the alternative scenario in which the material in the ultrastable state is actually an attempted realization of the low temperature ideal glass phase of the system that can be reached in some systems, like ST2 water and amorphous silicon, and model systems like the attractive Jagla model, by a first order thermodynamic transition. These are special in that they exhibit first order phase transitions to the ground state that are accessible above the normal Tg of the high temperature phase - and in consequence exhibit vanishingly small excess entropies over crystal, and none of the "ubiquitous" glassy state cryogenic anomalies. In particular we show how, near a liquid-liquid critical point, the diffusivity can decrease arbitrarily rapidly over several orders of magnitude and that a growth front transformation from ultraslow phase to normal viscous liquid will be very difficult to distinguish from nucleation and growth of a new phase of different mobility.
KW - Fragile-strong transition
KW - Liquid-glass phase transitions
KW - Liquid-liquid phase transitions
KW - Rotator phases with lambda transitions
KW - Ultrastable glasses
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U2 - 10.1016/j.jnoncrysol.2014.08.044
DO - 10.1016/j.jnoncrysol.2014.08.044
M3 - Article
AN - SCOPUS:84922355858
SN - 0022-3093
VL - 407
SP - 246
EP - 255
JO - Journal of Non-Crystalline Solids
JF - Journal of Non-Crystalline Solids
ER -