Molecular beam optical Stark study of the [18.1] 2Π 1/2 -X 4∑1/2- band system of rhodium monosulfide

Tongmei Ma; Hailing Wang; Timothy Steimle

doi:10.1063/1.2778683

Molecular beam optical Stark study of the [18.1] ²Π _1/2 -X ⁴∑_1/2^- band system of rhodium monosulfide

Tongmei Ma, Hailing Wang, Timothy Steimle

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The optical Stark effect in the R13R (0.5) branch feature of the [18.1] Π 12 2 -X 12 -4 (v′, v″ =0) band of rhodium monosulfide (RhS) has been recorded and analyzed to determine the permanent electric dipole moment μe of 3.40 (2) D for the ground X 12 -4 (v=0) state and an upper limit of 1.5 D for the [18.1] Π 12 2 state. Molecular orbital correlation diagrams are used to interpret the relative values of μe for RhN, RhO, and RhS. The Rh103 (I=12) magnetic hyperfine interaction in the X 12 -4 and [18.1] Π 12 2 states is analyzed.

Original language	English (US)
Article number	124311
Journal	Journal of Chemical Physics
Volume	127
Issue number	12
DOIs	https://doi.org/10.1063/1.2778683
State	Published - 2007

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Molecular beam optical Stark study of the [18.1] 2Π 1/2 -X 4∑1/2- band system of rhodium monosulfide",

abstract = "The optical Stark effect in the R13R (0.5) branch feature of the [18.1] Π 12 2 -X 12 -4 (v′, v″ =0) band of rhodium monosulfide (RhS) has been recorded and analyzed to determine the permanent electric dipole moment μe of 3.40 (2) D for the ground X 12 -4 (v=0) state and an upper limit of 1.5 D for the [18.1] Π 12 2 state. Molecular orbital correlation diagrams are used to interpret the relative values of μe for RhN, RhO, and RhS. The Rh103 (I=12) magnetic hyperfine interaction in the X 12 -4 and [18.1] Π 12 2 states is analyzed.",

author = "Tongmei Ma and Hailing Wang and Timothy Steimle",

note = "Funding Information: This work was supported by a grant from the Fundamental Interactions Branch, Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy (DE-FG0204ER15603). ",

year = "2007",

doi = "10.1063/1.2778683",

language = "English (US)",

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T1 - Molecular beam optical Stark study of the [18.1] 2Π 1/2 -X 4∑1/2- band system of rhodium monosulfide

AU - Ma, Tongmei

AU - Wang, Hailing

AU - Steimle, Timothy

N1 - Funding Information: This work was supported by a grant from the Fundamental Interactions Branch, Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy (DE-FG0204ER15603).

PY - 2007

Y1 - 2007

N2 - The optical Stark effect in the R13R (0.5) branch feature of the [18.1] Π 12 2 -X 12 -4 (v′, v″ =0) band of rhodium monosulfide (RhS) has been recorded and analyzed to determine the permanent electric dipole moment μe of 3.40 (2) D for the ground X 12 -4 (v=0) state and an upper limit of 1.5 D for the [18.1] Π 12 2 state. Molecular orbital correlation diagrams are used to interpret the relative values of μe for RhN, RhO, and RhS. The Rh103 (I=12) magnetic hyperfine interaction in the X 12 -4 and [18.1] Π 12 2 states is analyzed.

AB - The optical Stark effect in the R13R (0.5) branch feature of the [18.1] Π 12 2 -X 12 -4 (v′, v″ =0) band of rhodium monosulfide (RhS) has been recorded and analyzed to determine the permanent electric dipole moment μe of 3.40 (2) D for the ground X 12 -4 (v=0) state and an upper limit of 1.5 D for the [18.1] Π 12 2 state. Molecular orbital correlation diagrams are used to interpret the relative values of μe for RhN, RhO, and RhS. The Rh103 (I=12) magnetic hyperfine interaction in the X 12 -4 and [18.1] Π 12 2 states is analyzed.

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Molecular beam optical Stark study of the [18.1] ²Π _1/2 -X ⁴∑_1/2^- band system of rhodium monosulfide

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