Molecular-beam optical Stark spectroscopy of ScO

Jeffrey Shirley; Chris Scurlock; Timothy Steimle

doi:10.1063/1.459135

Molecular-beam optical Stark spectroscopy of ScO

Jeffrey Shirley, Chris Scurlock, Timothy Steimle

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

The molecular-beam optical Stark spectrum of the A ²Π(ṽ = 1)-X ²Σ⁺ (v = 0) band system of ScO has been recorded and analyzed. The experimentally determined permanent electric dipole moments of the A ²Π_3/2, A ²Π _1/2, and X ²Σ⁺ states are 4.06(3), 4.43(2), and 4.55(8) D, respectively. The determined hyperfine parameters for the A ²Π state are α = 135(1) MHz, d = 177(2) MHz, and eQq₀ = - 83( 12) MHz. The spectroscopic parameters are interpreted in terms of plausible models for the electronic nature of the A ²Π and X ²Σ⁺ states and are compared with theoretical values.

Original language	English (US)
Pages (from-to)	1568-1575
Number of pages	8
Journal	The Journal of chemical physics
Volume	93
Issue number	3
DOIs	https://doi.org/10.1063/1.459135
State	Published - 1990

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Molecular-beam optical Stark spectroscopy of ScO",

abstract = "The molecular-beam optical Stark spectrum of the A 2Π(ṽ = 1)-X 2Σ+ (v = 0) band system of ScO has been recorded and analyzed. The experimentally determined permanent electric dipole moments of the A 2Π3/2, A 2Π 1/2, and X 2Σ+ states are 4.06(3), 4.43(2), and 4.55(8) D, respectively. The determined hyperfine parameters for the A 2Π state are α = 135(1) MHz, d = 177(2) MHz, and eQq0 = - 83( 12) MHz. The spectroscopic parameters are interpreted in terms of plausible models for the electronic nature of the A 2Π and X 2Σ+ states and are compared with theoretical values.",

author = "Jeffrey Shirley and Chris Scurlock and Timothy Steimle",

year = "1990",

doi = "10.1063/1.459135",

language = "English (US)",

volume = "93",

pages = "1568--1575",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "3",

}

TY - JOUR

T1 - Molecular-beam optical Stark spectroscopy of ScO

AU - Shirley, Jeffrey

AU - Scurlock, Chris

AU - Steimle, Timothy

PY - 1990

Y1 - 1990

N2 - The molecular-beam optical Stark spectrum of the A 2Π(ṽ = 1)-X 2Σ+ (v = 0) band system of ScO has been recorded and analyzed. The experimentally determined permanent electric dipole moments of the A 2Π3/2, A 2Π 1/2, and X 2Σ+ states are 4.06(3), 4.43(2), and 4.55(8) D, respectively. The determined hyperfine parameters for the A 2Π state are α = 135(1) MHz, d = 177(2) MHz, and eQq0 = - 83( 12) MHz. The spectroscopic parameters are interpreted in terms of plausible models for the electronic nature of the A 2Π and X 2Σ+ states and are compared with theoretical values.

AB - The molecular-beam optical Stark spectrum of the A 2Π(ṽ = 1)-X 2Σ+ (v = 0) band system of ScO has been recorded and analyzed. The experimentally determined permanent electric dipole moments of the A 2Π3/2, A 2Π 1/2, and X 2Σ+ states are 4.06(3), 4.43(2), and 4.55(8) D, respectively. The determined hyperfine parameters for the A 2Π state are α = 135(1) MHz, d = 177(2) MHz, and eQq0 = - 83( 12) MHz. The spectroscopic parameters are interpreted in terms of plausible models for the electronic nature of the A 2Π and X 2Σ+ states and are compared with theoretical values.

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Molecular-beam optical Stark spectroscopy of ScO

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