Ligand-unsupported Au(I) chains with short Au(I)⋯Au(I) contacts

Shao Liang Zheng; Cara L. Nygren; Marc Messerschmidt; Philip Coppens

doi:10.1039/b606999a

Ligand-unsupported Au(I) chains with short Au(I)⋯Au(I) contacts

Shao Liang Zheng, Cara L. Nygren, Marc Messerschmidt, Philip Coppens

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

A new series of solids with ligand-unsupported Au(i) chains with short Au⋯Au contacts were synthesized; as Ag compounds with the same structure are known, the new phases now allow unbiased comparison of Ag⋯Ag and Au⋯Au metallophilic bonds not supported by bridging ligands, which shows the latter to be consistently shorter by 0.03-0.04 Å.

Original language	English (US)
Pages (from-to)	3711-3713
Number of pages	3
Journal	Chemical Communications
Issue number	35
DOIs	https://doi.org/10.1039/b606999a
State	Published - 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b606999a

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title = "Ligand-unsupported Au(I) chains with short Au(I)⋯Au(I) contacts",

abstract = "A new series of solids with ligand-unsupported Au(i) chains with short Au⋯Au contacts were synthesized; as Ag compounds with the same structure are known, the new phases now allow unbiased comparison of Ag⋯Ag and Au⋯Au metallophilic bonds not supported by bridging ligands, which shows the latter to be consistently shorter by 0.03-0.04 {\AA}.",

author = "Zheng, {Shao Liang} and Nygren, {Cara L.} and Marc Messerschmidt and Philip Coppens",

year = "2006",

doi = "10.1039/b606999a",

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journal = "Chemical Communications",

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T1 - Ligand-unsupported Au(I) chains with short Au(I)⋯Au(I) contacts

AU - Zheng, Shao Liang

AU - Nygren, Cara L.

AU - Messerschmidt, Marc

AU - Coppens, Philip

PY - 2006

Y1 - 2006

N2 - A new series of solids with ligand-unsupported Au(i) chains with short Au⋯Au contacts were synthesized; as Ag compounds with the same structure are known, the new phases now allow unbiased comparison of Ag⋯Ag and Au⋯Au metallophilic bonds not supported by bridging ligands, which shows the latter to be consistently shorter by 0.03-0.04 Å.

AB - A new series of solids with ligand-unsupported Au(i) chains with short Au⋯Au contacts were synthesized; as Ag compounds with the same structure are known, the new phases now allow unbiased comparison of Ag⋯Ag and Au⋯Au metallophilic bonds not supported by bridging ligands, which shows the latter to be consistently shorter by 0.03-0.04 Å.

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U2 - 10.1039/b606999a

DO - 10.1039/b606999a

M3 - Article

AN - SCOPUS:33748208273

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JO - Chemical Communications

JF - Chemical Communications

IS - 35

ER -

Ligand-unsupported Au(I) chains with short Au(I)⋯Au(I) contacts

Abstract

ASJC Scopus subject areas

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