Abstract
Addition of NaEt3BH to (Ph2PPrDI)CoCl2 affords the corresponding monohydride, (Ph2PPrDI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(ii) centre. Notably, (Ph2PPrDI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7333-7336 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 53 |
| DOIs | |
| State | Published - 2017 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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CCDC 1539444: Experimental Crystal Structure Determination
Ben-Daat, H. (Creator), Rock, C. L. (Creator), Flores, M. (Creator), Groy, T. L. (Creator), Bowman, A. C. (Creator) & Trovitch, R. J. (Creator), The Cambridge Structural Database, 2017
DOI: 10.5517/ccdc.csd.cc1nnxhq, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1nnxhq&sid=DataCite
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