Highly conducting Li+-rich inorganic glasses

S. I. Smedley; C. A. Angell

doi:10.1016/0038-1098(78)91042-6

Highly conducting Li⁺-rich inorganic glasses

S. I. Smedley, C. A. Angell

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Several glasses containing B₂O₃ with combinations of lithium oxide and lithium salts are shown to have unusually high electrical conductivities. At 200°C they exceed those of all but the most successful polycrystalline lithium conductors. Glasses containing as little as 15 mol % B₂O₃ are included, but the exceedingly high Li⁺ contents in such glasses appear detrimental to conductivity.

Original language	English (US)
Pages (from-to)	21-23
Number of pages	3
Journal	Solid State Communications
Volume	27
Issue number	1
DOIs	https://doi.org/10.1016/0038-1098(78)91042-6
State	Published - Jul 1978
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Materials Chemistry

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10.1016/0038-1098(78)91042-6

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title = "Highly conducting Li+-rich inorganic glasses",

abstract = "Several glasses containing B2O3 with combinations of lithium oxide and lithium salts are shown to have unusually high electrical conductivities. At 200°C they exceed those of all but the most successful polycrystalline lithium conductors. Glasses containing as little as 15 mol % B2O3 are included, but the exceedingly high Li+ contents in such glasses appear detrimental to conductivity.",

author = "Smedley, {S. I.} and Angell, {C. A.}",

note = "Funding Information: Acknowledgement - This research was supported by the National Science Foundation (MRL program DMR76-O0889-A01). Glass preparations were assisted by D. Blough and D. Ringoen.",

year = "1978",

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AU - Smedley, S. I.

AU - Angell, C. A.

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Y1 - 1978/7

N2 - Several glasses containing B2O3 with combinations of lithium oxide and lithium salts are shown to have unusually high electrical conductivities. At 200°C they exceed those of all but the most successful polycrystalline lithium conductors. Glasses containing as little as 15 mol % B2O3 are included, but the exceedingly high Li+ contents in such glasses appear detrimental to conductivity.

AB - Several glasses containing B2O3 with combinations of lithium oxide and lithium salts are shown to have unusually high electrical conductivities. At 200°C they exceed those of all but the most successful polycrystalline lithium conductors. Glasses containing as little as 15 mol % B2O3 are included, but the exceedingly high Li+ contents in such glasses appear detrimental to conductivity.

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Highly conducting Li⁺-rich inorganic glasses

Abstract

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