Hammett analysis of absolute carbene addition rate constants

R. A. Moss; L. A. Perez; N. J. Turro; I. R. Gould; N. P. Hacker

doi:10.1016/S0040-4039(00)81498-7

Hammett analysis of absolute carbene addition rate constants

R. A. Moss, L. A. Perez, N. J. Turro, I. R. Gould, N. P. Hacker

Research output: Contribution to journal › Article › peer-review

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Abstract

Absolute rate constants were determined for the additions of 5 5-X-substituted ArCCl (X=CF₃, Cl, H, CH₃, CH₃O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ{variant} = +1.4 - 1.6.

Original language	English (US)
Pages (from-to)	685-688
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	7
DOIs	https://doi.org/10.1016/S0040-4039(00)81498-7
State	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Hammett analysis of absolute carbene addition rate constants",

abstract = "Absolute rate constants were determined for the additions of 5 5-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ{variant} = +1.4 - 1.6.",

author = "Moss, {R. A.} and Perez, {L. A.} and Turro, {N. J.} and Gould, {I. R.} and Hacker, {N. P.}",

year = "1983",

doi = "10.1016/S0040-4039(00)81498-7",

language = "English (US)",

volume = "24",

pages = "685--688",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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T1 - Hammett analysis of absolute carbene addition rate constants

AU - Moss, R. A.

AU - Perez, L. A.

AU - Turro, N. J.

AU - Gould, I. R.

AU - Hacker, N. P.

PY - 1983

Y1 - 1983

N2 - Absolute rate constants were determined for the additions of 5 5-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ{variant} = +1.4 - 1.6.

AB - Absolute rate constants were determined for the additions of 5 5-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ{variant} = +1.4 - 1.6.

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U2 - 10.1016/S0040-4039(00)81498-7

DO - 10.1016/S0040-4039(00)81498-7

M3 - Article

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SP - 685

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 7

ER -

Hammett analysis of absolute carbene addition rate constants

Abstract

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