TY - JOUR
T1 - Group contribution values of the infinite dilution thermodynamic functions of hydration for aliphatic noncyclic hydrocarbons, alcohols, and ketones at 298.15 K and 0.1 MPa
AU - Plyasunov, Andrey V.
AU - Shock, Everett L.
PY - 2001/9
Y1 - 2001/9
N2 - A compilation of experimental values of the infinite dilution partial molar Gibbs energy, enthalpy, and heat capacity of hydration, together with molar volumes in water at 298.15 K and 0.1 MPa, is presented for aliphatic noncyclic ketones. These data, combined with the related results for aliphatic noncyclic hydrocarbons and monohydric alcohols, were treated in the framework of a simple first-order group additivity scheme. Numerical values of the contributions to each of the thermodynamic properties are obtained by the least-squares procedure for the following groups: CH3, CH2, CH, C, OH, and CO.
AB - A compilation of experimental values of the infinite dilution partial molar Gibbs energy, enthalpy, and heat capacity of hydration, together with molar volumes in water at 298.15 K and 0.1 MPa, is presented for aliphatic noncyclic ketones. These data, combined with the related results for aliphatic noncyclic hydrocarbons and monohydric alcohols, were treated in the framework of a simple first-order group additivity scheme. Numerical values of the contributions to each of the thermodynamic properties are obtained by the least-squares procedure for the following groups: CH3, CH2, CH, C, OH, and CO.
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U2 - 10.1021/je0002282
DO - 10.1021/je0002282
M3 - Article
AN - SCOPUS:0035437780
SN - 0021-9568
VL - 46
SP - 1016
EP - 1019
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 5
ER -