Electron transfer in molecules with conformational transitions

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14 Scopus citations


Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains, besides the activation enthalpy, a temperature-dependent entropic term ΔS=a1+a2T.

Original languageEnglish (US)
Pages (from-to)131-136
Number of pages6
JournalChemical Physics Letters
Issue number2-3
StatePublished - Feb 19 1993
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry


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