Einkristalluntersuchungen an LiMF 6 (M = Rh, Ir), Li 2RhF 6 und K 2IrF 6

H. Fitz; B. G. Müller; O. Graudejus; N. Bartlett

doi:10.1002/1521-3749(200201)628:1<133::AID-ZAAC133>3.0.CO;2-S

Einkristalluntersuchungen an LiMF ₆ (M = Rh, Ir), Li ₂RhF ₆ und K ₂IrF ₆

Translated title of the contribution: Single crystal investigations on LiMF ₆ (M = Rh, Ir), Li ₂RhF ₆, and K ₂IrF ₆

H. Fitz, B. G. Müller, O. Graudejus, N. Bartlett

Arizona State University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

LiRhF ₆, LiIrF ₆, Li ₂RhF ₆, and K ₂IrF ₆ were obtained again, but for the first time investigated by single crystal X-ray methods. Rubyred LiRhF ₆ and yellow LiIrF ₆ crystallize isostructural in the trigonal space group R3̄ - C _3i ² (Nr. 148) with the lattice parameters LiRhF ₆: a = 502.018(7) pm, c = 1355.88(3) pm, Z = 3 and d(Rh-F) = 185.5(1) pm; LiIrF ₆: a = 506.148(4) pm, c = 1362.60(2) pm, Z = 3, d(Ir-F) = 187.5(3) pm (LiSbF ₆-Typ). Yellow Li ₂RhF ₆ crystallizes tetragonal in the space group P4 ₂/mnm - D _4h ¹⁴ (Nr. 136) with a = 463.880(8) pm, c = 905.57(2) pm, Z = 2 and d(Rh-F) = 190.3(4)-191.4(3) pm (Trirutil-Typ). Yellow K ₂IrF ₆ crystallizes trigonal in the space group P3̄m1 - D _3d ³ (Nr. 164) with a = 578.88(7) pm, c = 465.06(5) pm, Z = 1 and d(Ir-F) = 194.0(6) pm, isotypic with K ₂GeF ₆.

Translated title of the contribution	Single crystal investigations on LiMF ₆ (M = Rh, Ir), Li ₂RhF ₆, and K ₂IrF ₆
Original language	German
Pages (from-to)	133-137
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	628
Issue number	1
DOIs	https://doi.org/10.1002/1521-3749(200201)628:1<133::AID-ZAAC133>3.0.CO;2-S
State	Published - Aug 23 2002

Keywords

Crystral structure
Fluoroiridates
Fluororhodates
Iridium
Rhodium

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/1521-3749(200201)628:1<133::AID-ZAAC133>3.0.CO;2-S

Cite this

@article{ae9b114e77b64afa9051e2cb779456c1,

title = "Einkristalluntersuchungen an LiMF 6 (M = Rh, Ir), Li 2RhF 6 und K 2IrF 6 ",

abstract = "LiRhF 6, LiIrF 6, Li 2RhF 6, and K 2IrF 6 were obtained again, but for the first time investigated by single crystal X-ray methods. Rubyred LiRhF 6 and yellow LiIrF 6 crystallize isostructural in the trigonal space group R{\=3} - C 3i 2 (Nr. 148) with the lattice parameters LiRhF 6: a = 502.018(7) pm, c = 1355.88(3) pm, Z = 3 and d(Rh-F) = 185.5(1) pm; LiIrF 6: a = 506.148(4) pm, c = 1362.60(2) pm, Z = 3, d(Ir-F) = 187.5(3) pm (LiSbF 6-Typ). Yellow Li 2RhF 6 crystallizes tetragonal in the space group P4 2/mnm - D 4h 14 (Nr. 136) with a = 463.880(8) pm, c = 905.57(2) pm, Z = 2 and d(Rh-F) = 190.3(4)-191.4(3) pm (Trirutil-Typ). Yellow K 2IrF 6 crystallizes trigonal in the space group P{\=3}m1 - D 3d 3 (Nr. 164) with a = 578.88(7) pm, c = 465.06(5) pm, Z = 1 and d(Ir-F) = 194.0(6) pm, isotypic with K 2GeF 6.",

keywords = "Crystral structure, Fluoroiridates, Fluororhodates, Iridium, Rhodium",

author = "H. Fitz and M{\"u}ller, {B. G.} and O. Graudejus and N. Bartlett",

year = "2002",

month = aug,

day = "23",

doi = "10.1002/1521-3749(200201)628:1<133::AID-ZAAC133>3.0.CO;2-S",

language = "German",

volume = "628",

pages = "133--137",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - Einkristalluntersuchungen an LiMF 6 (M = Rh, Ir), Li 2RhF 6 und K 2IrF 6

AU - Fitz, H.

AU - Müller, B. G.

AU - Graudejus, O.

AU - Bartlett, N.

PY - 2002/8/23

Y1 - 2002/8/23

N2 - LiRhF 6, LiIrF 6, Li 2RhF 6, and K 2IrF 6 were obtained again, but for the first time investigated by single crystal X-ray methods. Rubyred LiRhF 6 and yellow LiIrF 6 crystallize isostructural in the trigonal space group R3̄ - C 3i 2 (Nr. 148) with the lattice parameters LiRhF 6: a = 502.018(7) pm, c = 1355.88(3) pm, Z = 3 and d(Rh-F) = 185.5(1) pm; LiIrF 6: a = 506.148(4) pm, c = 1362.60(2) pm, Z = 3, d(Ir-F) = 187.5(3) pm (LiSbF 6-Typ). Yellow Li 2RhF 6 crystallizes tetragonal in the space group P4 2/mnm - D 4h 14 (Nr. 136) with a = 463.880(8) pm, c = 905.57(2) pm, Z = 2 and d(Rh-F) = 190.3(4)-191.4(3) pm (Trirutil-Typ). Yellow K 2IrF 6 crystallizes trigonal in the space group P3̄m1 - D 3d 3 (Nr. 164) with a = 578.88(7) pm, c = 465.06(5) pm, Z = 1 and d(Ir-F) = 194.0(6) pm, isotypic with K 2GeF 6.

AB - LiRhF 6, LiIrF 6, Li 2RhF 6, and K 2IrF 6 were obtained again, but for the first time investigated by single crystal X-ray methods. Rubyred LiRhF 6 and yellow LiIrF 6 crystallize isostructural in the trigonal space group R3̄ - C 3i 2 (Nr. 148) with the lattice parameters LiRhF 6: a = 502.018(7) pm, c = 1355.88(3) pm, Z = 3 and d(Rh-F) = 185.5(1) pm; LiIrF 6: a = 506.148(4) pm, c = 1362.60(2) pm, Z = 3, d(Ir-F) = 187.5(3) pm (LiSbF 6-Typ). Yellow Li 2RhF 6 crystallizes tetragonal in the space group P4 2/mnm - D 4h 14 (Nr. 136) with a = 463.880(8) pm, c = 905.57(2) pm, Z = 2 and d(Rh-F) = 190.3(4)-191.4(3) pm (Trirutil-Typ). Yellow K 2IrF 6 crystallizes trigonal in the space group P3̄m1 - D 3d 3 (Nr. 164) with a = 578.88(7) pm, c = 465.06(5) pm, Z = 1 and d(Ir-F) = 194.0(6) pm, isotypic with K 2GeF 6.

KW - Crystral structure

KW - Fluoroiridates

KW - Fluororhodates

KW - Iridium

KW - Rhodium

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JO - Zeitschrift fur Anorganische und Allgemeine Chemie

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