Efficient atomic-scale kinetics through a complex heterophase interface

Atomic-scale imaging and first-principles modeling are applied to the heterophase interface between the Al-Cu solid solution (α_Cu) and θ^′ (Al₂Cu) phases. Contrary to recent studies, our observations reveal a diffuse interface of complex but well-defined structure that enables the progression from α_Cu to θ^′ over a distance of ≈1 nm. We demonstrate that, surprisingly, the observed interfacial structure is not preferred on energetic grounds. Rather, the excess in interfacial energy is compensated by efficient atomic-scale kinetics of the α_Cu→θ^′ phase transformation.