Effect of surface deposited Pt on the photoactivity of TiO 2

Christopher L. Muhich, Yun Zhou, Aaron M. Holder, Alan W. Weimer, Charles B. Musgrave

Research output: Contribution to journalArticlepeer-review

91 Scopus citations


The roles of deposited Pt clusters and adsorbed O 2 in the photoactivity of anatase TiO 2 (101) surfaces have been studied using density functional theory. O 2 only adsorbs to TiO 2 surfaces when excess negative charge is available to form O-Ti bonds, which can be provided by a photoexcited electron or subsurface oxygen vacancy, in which cases the adsorption energies are -0.94 and -2.52 eV, respectively. When O 2 adsorbs near a subsurface defect, it scavenges extra electron density and creates a hole that can annihilate excited electrons. In aqueous solutions, O 2 interactions with the TiO 2 surface are rare because water preferentially adsorbs at the surface. Pt clusters on TiO 2 significantly enhance O 2 adsorption providing many adsorption sites with adsorption energies up to -1.69 eV, stronger than the -0.52 eV adsorption energy of H 2O on the Pt cluster. Consequently, Pt increases the rate of electron scavenging by O 2 relative to that of undoped TiO 2 leading to enhanced photocatalytic performance. Pt states completely bridge the band gap and act as electron-hole recombination centers, which are deleterious to the photoactivity of TiO 2. The initial rise and subsequent fall in TiO 2's photoactivity with Pt loading results from the competition between enhanced electron scavenging due to increased O 2 adsorption and increased electron-hole recombination.

Original languageEnglish (US)
Pages (from-to)10138-10149
Number of pages12
JournalJournal of Physical Chemistry C
Issue number18
StatePublished - May 10 2012
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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