A microwave-optical double resonance spectroscopic study of TiO and TiN

Timothy Steimle; J. E. Shirley; K. Y. Jung; L. R. Russon; C. T. Scurlock

doi:10.1016/0022-2852(90)90305-A

A microwave-optical double resonance spectroscopic study of TiO and TiN

Timothy Steimle, J. E. Shirley, K. Y. Jung, L. R. Russon, C. T. Scurlock

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X³Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X²Σ⁺) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.

Original language	English (US)
Pages (from-to)	27-31
Number of pages	5
Journal	Journal of molecular spectroscopy
Volume	144
Issue number	1
DOIs	https://doi.org/10.1016/0022-2852(90)90305-A
State	Published - Nov 1990

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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@article{317a1d2a7a484db09f12b4afcb4826f2,

title = "A microwave-optical double resonance spectroscopic study of TiO and TiN",

abstract = "The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.",

author = "Timothy Steimle and Shirley, {J. E.} and Jung, {K. Y.} and Russon, {L. R.} and Scurlock, {C. T.}",

note = "Funding Information: This work was supported by a grant from the National Science Foundation ( CHE 871 3927) We thank Professor David Harris (U.C. Santa Barbara), Dr. Barry Turner (NRAO), and Dr. J. M. Brown (Physical Chemistry Laboratory-Oxford) for the loan of microwave equipment.",

year = "1990",

month = nov,

doi = "10.1016/0022-2852(90)90305-A",

language = "English (US)",

volume = "144",

pages = "27--31",

journal = "Journal of molecular spectroscopy",

issn = "0022-2852",

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TY - JOUR

T1 - A microwave-optical double resonance spectroscopic study of TiO and TiN

AU - Steimle, Timothy

AU - Shirley, J. E.

AU - Jung, K. Y.

AU - Russon, L. R.

AU - Scurlock, C. T.

N1 - Funding Information: This work was supported by a grant from the National Science Foundation ( CHE 871 3927) We thank Professor David Harris (U.C. Santa Barbara), Dr. Barry Turner (NRAO), and Dr. J. M. Brown (Physical Chemistry Laboratory-Oxford) for the loan of microwave equipment.

PY - 1990/11

Y1 - 1990/11

N2 - The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.

AB - The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.

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A microwave-optical double resonance spectroscopic study of TiO and TiN

Abstract

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